Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency
文献类型：期刊论文
| 作者 | Fan, Qunping1; Su, Wenyan1; Wang, Yan1; Guo, Bing1; Jiang, Yufeng3; Guo, Xia1; Liu, Feng2; Russell, Thomas P.3; Zhang, Maojie1; Li, Yongfang4 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 61期号:5页码:531-537 |
| 关键词 | Polymer Solar Cells Fluorine Substitution Non-fullerene Wide Bandgap Conjugated Polymer Power Conversion Efficiency |
| ISSN号 | 1674-7291 |
| DOI | 10.1007/s11426-017-9199-1 |
| 英文摘要 | A high performance polymer solar cells (PSCs) based on polymer donor PM6 containing fluorinated thienyl benzodithiophene unit and n-type organic semiconductor acceptor IT-4F containing fluorinated end-groups were developed. In addition to complementary absorption spectra (300-830 nm) with IT-4F, the PM6 also has a deep HOMO (the highest occupied molecular) level (-5.50 eV), which will lower the open-circuit voltage (V-oc) sacrifice and reduce the E-loss of the IT-4F-based PSCs. Moreover, the strong crystallinity of PM6 is beneficial to form favorable blend morphology and hence to suppress recombination. As a result, in comparison with the PSCs based on a non-fluorinated D/A pair of PBDB-T:ITIC with a medium PCE of 11.2%, the PM6:IT-4Fbased PSCs yielded an impressive PCE of 13.5% due to the synergistic effect of fluorination on both donor and acceptor, which is among the highest values recorded in the literatures for PSCs to date. Furthermore, a PCE of 12.2% was remained with the active layer thickness of up to 285 nm and a high PCE of 11.4% was also obtained with a large device area of 1 cm(2). In addition, the devices also showed good storage, thermal and illumination stabilities with respect to the efficiency. These results indicate that fluorination is an effective strategy to improve the photovoltaic performance of materials, as well as the both fluorinated donor and acceptor pair-PM6:IT-4F is an ideal candidate for the large scale roll-to-roll production of efficient PSCs in the future. |
| 语种 | 英语 |
| WOS记录号 | WOS:000431179300007 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43181]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Maojie |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, State & Local Joint Engn Lab Novel Funct Polymer, Lab Adv Optoelect Mat, Suzhou 215123, Peoples R China 2.Shanghai Jiao Tong Univ, Dept Phys & Astron, Collaborat Innovat Ctr IFSA, Shanghai 200240, Peoples R China 3.Lawrence Berkeley Natl Lab, Mat Sci Div, Berkeley, CA 94720 USA 4.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Qunping,Su, Wenyan,Wang, Yan,et al. Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency[J]. SCIENCE CHINA-CHEMISTRY,2018,61(5):531-537. |
| APA | Fan, Qunping.,Su, Wenyan.,Wang, Yan.,Guo, Bing.,Jiang, Yufeng.,...&Li, Yongfang.(2018).Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency.SCIENCE CHINA-CHEMISTRY,61(5),531-537. |
| MLA | Fan, Qunping,et al."Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency".SCIENCE CHINA-CHEMISTRY 61.5(2018):531-537. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。