中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways

文献类型:期刊论文

作者Zeng, Xiangze1; Li, Zhan-Wei2; Zheng, Xiaoyan1; Zhu, Lizhe1; Sun, Zhao-Yan2; Lu, Zhong-Yuan3; Huang, Xuhui1
刊名PHYSICAL CHEMISTRY CHEMICAL PHYSICS
出版日期2018-04-21
卷号20期号:15页码:10030-10037
ISSN号1463-9076
DOI10.1039/c8cp00522b
英文摘要Hollow polyhedral cages hold great potential for application in nanotechnological and biomedical fields. Understanding the formation mechanism of these self-assembled structures could provide guidance for the rational design of the desired polyhedral cages. Here, by constructing kinetic network models from extensive coarse-grained molecular dynamics simulations, we elucidated the formation mechanism of the dodecahedral cage, which is formed by the self-assembly of patchy particles. We found that the dodecahedral cage is formed through increasing the aggregate size followed by structure rearrangement. Based on this mechanistic understanding, we improved the productivity of the dodecahedral cage through the rational design of the patch arrangement of patchy particles, which promotes the structural rearrangement process. Our results demonstrate that it should be a feasible strategy to achieve the rational design of the desired nanostructures via the kinetic analysis. We anticipate that this methodology could be extended to other self-assembly systems for the fabrication of functional nanomaterials.
语种英语
WOS记录号WOS:000430537600035
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/43223]  
专题中国科学院化学研究所
通讯作者Li, Zhan-Wei; Huang, Xuhui
作者单位1.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun, Jilin, Peoples R China
3.Jilin Univ, Inst Theoret Chem, State Key Lab Supramol Struct & Mat, Changchun, Jilin, Peoples R China
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GB/T 7714
Zeng, Xiangze,Li, Zhan-Wei,Zheng, Xiaoyan,et al. Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(15):10030-10037.
APA Zeng, Xiangze.,Li, Zhan-Wei.,Zheng, Xiaoyan.,Zhu, Lizhe.,Sun, Zhao-Yan.,...&Huang, Xuhui.(2018).Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(15),10030-10037.
MLA Zeng, Xiangze,et al."Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.15(2018):10030-10037.

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来源:化学研究所

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