Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways
文献类型：期刊论文
| 作者 | Zeng, Xiangze1; Li, Zhan-Wei2; Zheng, Xiaoyan1; Zhu, Lizhe1; Sun, Zhao-Yan2; Lu, Zhong-Yuan3; Huang, Xuhui1 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2018-04-21 |
| 卷号 | 20期号:15页码:10030-10037 |
| ISSN号 | 1463-9076 |
| DOI | 10.1039/c8cp00522b |
| 英文摘要 | Hollow polyhedral cages hold great potential for application in nanotechnological and biomedical fields. Understanding the formation mechanism of these self-assembled structures could provide guidance for the rational design of the desired polyhedral cages. Here, by constructing kinetic network models from extensive coarse-grained molecular dynamics simulations, we elucidated the formation mechanism of the dodecahedral cage, which is formed by the self-assembly of patchy particles. We found that the dodecahedral cage is formed through increasing the aggregate size followed by structure rearrangement. Based on this mechanistic understanding, we improved the productivity of the dodecahedral cage through the rational design of the patch arrangement of patchy particles, which promotes the structural rearrangement process. Our results demonstrate that it should be a feasible strategy to achieve the rational design of the desired nanostructures via the kinetic analysis. We anticipate that this methodology could be extended to other self-assembly systems for the fabrication of functional nanomaterials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000430537600035 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43223]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zhan-Wei; Huang, Xuhui |
| 作者单位 | 1.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun, Jilin, Peoples R China 3.Jilin Univ, Inst Theoret Chem, State Key Lab Supramol Struct & Mat, Changchun, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zeng, Xiangze,Li, Zhan-Wei,Zheng, Xiaoyan,et al. Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(15):10030-10037. |
| APA | Zeng, Xiangze.,Li, Zhan-Wei.,Zheng, Xiaoyan.,Zhu, Lizhe.,Sun, Zhao-Yan.,...&Huang, Xuhui.(2018).Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(15),10030-10037. |
| MLA | Zeng, Xiangze,et al."Improving the productivity of monodisperse polyhedral cages by the rational design of kinetic self-assembly pathways".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.15(2018):10030-10037. |
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来源：化学研究所
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