Rational design of hierarchical ZnO@Carbon nanoflower for high performance lithium ion battery anodes
文献类型：期刊论文
| 作者 | Liu, Huichao1,2; Shi, Ludi1; Li, Dongzhi1; Yu, Jiali1; Zhang, Han-Ming1; Ullah, Shahid1; Yang, Bo1; Li, Cuihua1; Zhu, Caizhen1; Xu, Jian2 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2018-05-31 |
| 卷号 | 387页码:64-71 |
| ISSN号 | 0378-7753 |
| 关键词 | Zinc Oxide Nanoflower Micro-nano Secondary Structure Dopamine Carbon Coating Anode Material |
| DOI | 10.1016/j.jpowsour.2018.03.047 |
| 英文摘要 | The rational structure design and strong interfacial bonding are crucially desired for high performance zinc oxide (ZnO)/carbon composite electrodes. In this context, micro-nano secondary structure design and strong dopamine coating strategies are adopted for the fabrication of flower-like ZnO/carbon (ZnO@C nanoflowers) composite electrodes. The results show the ZnO@C nanoflowers (2-6 mu m) are assembled by hierarchical ZnO nanosheets similar to 27 nm) and continuous carbon framework. The micro-nano secondary architecture can facilitate the penetration of electrolyte, shorten lithium ions diffusion length, and hinder the aggregation of the nanosheets. Moreover, the strong chemical interaction between ZnO and coating carbon layer via C-Zn bond improves structure stability as well as the electronic conductivity. As a synergistic result, when evaluated as lithium ion batteries (LIBs) anode, the ZnO@C nanoflower electrodes show high reversible capacity of ca. 1200 mA h g(-1) at 0.1 A g(-1) after 80 cycles. As well as good long-cycling stability (638 and 420 mA h g(-1) at 1 and 5 A g(-1) after 500 cycles, respectively) and excellent rate capability. Therefore, this rational design of ZnO@C nanoflowers electrode is a promising anode for high-performance LIBs. |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000430899800009 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43229]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, Caizhen |
| 作者单位 | 1.Shenzhen Univ, Dept Chem & Environm Engn, Shenzhen 518060, Guangdong, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Huichao,Shi, Ludi,Li, Dongzhi,et al. Rational design of hierarchical ZnO@Carbon nanoflower for high performance lithium ion battery anodes[J]. JOURNAL OF POWER SOURCES,2018,387:64-71. |
| APA | Liu, Huichao.,Shi, Ludi.,Li, Dongzhi.,Yu, Jiali.,Zhang, Han-Ming.,...&Xu, Jian.(2018).Rational design of hierarchical ZnO@Carbon nanoflower for high performance lithium ion battery anodes.JOURNAL OF POWER SOURCES,387,64-71. |
| MLA | Liu, Huichao,et al."Rational design of hierarchical ZnO@Carbon nanoflower for high performance lithium ion battery anodes".JOURNAL OF POWER SOURCES 387(2018):64-71. |
入库方式： OAI收割
来源：化学研究所
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