Junction-Controlled Topological Polymerization
文献类型：期刊论文
| 作者 | Li, Mao1; Kang, Shusen1; Du, Jia1; Zhang, Jian1; Wang, Jinxin1; Ariga, Katsuhiko2,3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-04-23 |
| 卷号 | 57期号:18页码:4936-4939 |
| 关键词 | Carbazoles C-c Coupling Polymerization Radical Coupling Topological Control |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201713026 |
| 英文摘要 | Methodology that enables the controlled synthesis of linear and branched polymers from an identical monomer will be a novel pathway for polymer synthesis and processing. Herein we first describe the control of one or both of the C(3)-C(3) and C(6)-C(6) coupling reactions of carbazolyl. In a second approach, an identical monomer containing two carbazolyls is polymerized using chemical and electrochemical oxidizers, leading to topologically controllable growth of linear polymers in weak oxidizer or of cross-linked polymer chains in strong oxidizer, with satisfactory long chain propagation of step growth polymerization (M-n=6.0x10(4)gmol(-1), M-w/M-n=2.3). This very simple polymerization with cheap reagents and low levels of waste has provided a flexible pathway for synthesis and processing of polymers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000432382800017 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43269]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Mao |
| 作者单位 | 1.Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China 2.Natl Inst Mat Sci, World Premier Int Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan 3.Univ Tokyo, Grad Sch Frontier Sci, Kashica 2770827, Japan |
| 推荐引用方式 GB/T 7714 | Li, Mao,Kang, Shusen,Du, Jia,et al. Junction-Controlled Topological Polymerization[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(18):4936-4939. |
| APA | Li, Mao,Kang, Shusen,Du, Jia,Zhang, Jian,Wang, Jinxin,&Ariga, Katsuhiko.(2018).Junction-Controlled Topological Polymerization.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(18),4936-4939. |
| MLA | Li, Mao,et al."Junction-Controlled Topological Polymerization".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.18(2018):4936-4939. |
入库方式： OAI收割
来源：化学研究所
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