Synthesis from Molecule into 3D Polyamide 6 Microspheres Stacked Polyhedrons via Self-Assembly
文献类型：期刊论文
| 作者 | Liu, Yan1; Duan, Jianping2; Xia, Housheng3; Xu, Jian4; Yang, Guisheng3 |
| 刊名 | MACROMOLECULAR MATERIALS AND ENGINEERING
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 303期号:5 |
| 关键词 | 3d Phase Version Polyamide Microspheres Polyhedrons Self-assembly |
| ISSN号 | 1438-7492 |
| DOI | 10.1002/mame.201700546 |
| 英文摘要 | Self-assembly provides the basis for a procedure used to organize larger objects into regular, 3D microsphere stacked polyhedrons. A novel approach is described for the fabrication of 3D structured micrometer-scale polyhedrons which are packed with nanosized spheres in the order of 400 nm by in situ polymerization using phase inversion technology. The extended polyhedrons can assemble into decimeter-level ordered materials. The side length of an individual polyhedron can be effectively tuned from 10 to 100 mu m through several ways. This method realizes directly self-assembly from molecule to regular extended polyhedrons materials. The process is primarily based on in situ anion polymerization of lactam in two-phase system whose self-assembly is driven by hydrogen bonds' force and polyethylene glycol stepwise crystallization synergistically. The results suggest that this strategy for self-assembly can be applied to design nonplanar complex geometric structure materials. In the future, polyhedrons packed with microspheres may be possible to build more complex 3D, self-assembly device modules for advanced materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000432026700002 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43299]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Yantai Univ, Dept Food & Biol Engn, Wenjing Coll, Yantai 264005, Peoples R China 2.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China 3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yan,Duan, Jianping,Xia, Housheng,et al. Synthesis from Molecule into 3D Polyamide 6 Microspheres Stacked Polyhedrons via Self-Assembly[J]. MACROMOLECULAR MATERIALS AND ENGINEERING,2018,303(5). |
| APA | Liu, Yan,Duan, Jianping,Xia, Housheng,Xu, Jian,&Yang, Guisheng.(2018).Synthesis from Molecule into 3D Polyamide 6 Microspheres Stacked Polyhedrons via Self-Assembly.MACROMOLECULAR MATERIALS AND ENGINEERING,303(5). |
| MLA | Liu, Yan,et al."Synthesis from Molecule into 3D Polyamide 6 Microspheres Stacked Polyhedrons via Self-Assembly".MACROMOLECULAR MATERIALS AND ENGINEERING 303.5(2018). |
入库方式： OAI收割
来源：化学研究所
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