Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion
文献类型：期刊论文
| 作者 | Huang, Zhijun1,2; Li, Fengbo1; Chen, Bingfeng1,2; Lu, Tao1,2; Yuan, Yin1,2; Yuan, Guoqing1 |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2013-06-05 |
| 卷号 | 136页码:269-277 |
| 关键词 | Heterogeneous Catalysis Carbides Nanomaterials Fixation Of Carbon Dioxide Cycloaddition |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2013.01.057 |
| 英文摘要 | Well-dispersed g-C3N4 nanophases in SBA-15 mesochannels were prepared by a two-step vapor condensation of dicyandiamide. Defect-containing g-C3N4 nanophases were active catalysts for CO2 activation. Activated CO2 species were steadily converted to target compounds with a high selectivity. The presence of doped metal ions markedly promoted the catalytic activity and selectivity. Zn2+-doped g-C3N4/SBA-15 showed a high activity in transferring CO2 to epoxides. Fe3+-doped g-C3N4/SBA-15 was an efficient catalyst for the direct oxidative cycloadditon of CO2 to olefins. Styrene was converted into 4-phenyl-1, 3-dioxolan-2-one. The process conversion was 34.1% and the selectivity to the oxidative cycloaddidon product reached 93%. The recyclability of SBA-15 supported g-C3N4 nanophases was investigated through a five-run test. Their catalytic activity and microstructures were kept constant during the five-run recycling test. No marked metal leaching was detected during each test. (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317539400031 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43325]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Fengbo |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Lab New Mat Inst Chem, Beijing, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Zhijun,Li, Fengbo,Chen, Bingfeng,et al. Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2013,136:269-277. |
| APA | Huang, Zhijun,Li, Fengbo,Chen, Bingfeng,Lu, Tao,Yuan, Yin,&Yuan, Guoqing.(2013).Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion.APPLIED CATALYSIS B-ENVIRONMENTAL,136,269-277. |
| MLA | Huang, Zhijun,et al."Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion".APPLIED CATALYSIS B-ENVIRONMENTAL 136(2013):269-277. |
入库方式： OAI收割
来源：化学研究所
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