Mechanistic Insights into N-N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides
文献类型：期刊论文
| 作者 | Xu, Ling1; Wang, Yu-Chen1; Ma, Wangyang1; Zhang, Wen-Xiong1,2; Xi, Zhenfeng1 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-12-19 |
| 卷号 | 79期号:24页码:12004-12009 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo501865b |
| 英文摘要 | Cleavage of the NN bond in 1,2-diarylhydrazine was achieved through an alkyllithium-catalyzed guanylation reaction of 1,2-diarylhydrazine with carbodiimide, affording guanidine and azo compounds. This NN bond cleavage via thermal rearrangement was driven by an intramolecular proton shift. No reductants, oxidants, bases, or external protons were needed. The proposed mechanism has been well elucidated by the isolation, characterization, and reaction studies of two important amido lithium intermediates and an ArHN-substituted guanidine. |
| 语种 | 英语 |
| WOS记录号 | WOS:000346759500018 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43477]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem, MOE Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Ling,Wang, Yu-Chen,Ma, Wangyang,et al. Mechanistic Insights into N-N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(24):12004-12009. |
| APA | Xu, Ling,Wang, Yu-Chen,Ma, Wangyang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Mechanistic Insights into N-N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides.JOURNAL OF ORGANIC CHEMISTRY,79(24),12004-12009. |
| MLA | Xu, Ling,et al."Mechanistic Insights into N-N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides".JOURNAL OF ORGANIC CHEMISTRY 79.24(2014):12004-12009. |
入库方式： OAI收割
来源：化学研究所
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