An optically active pentacoordinate silicate: (+)-bis(triethylammonium) bis-[(R,R)-tartrato(4-)]diphenyldisilicate
文献类型：期刊论文
| 作者 | Wang, ZG; Liu, SG; Wang, D; Sui, XM |
| 刊名 | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
 |
| 出版日期 | 1996-12-15 |
| 卷号 | 52页码:3179-3181 |
| ISSN号 | 0108-2701 |
| 英文摘要 | The title compound, 2C(6)H(16)N(+).C20H14O12Si22-, was prepared by the reaction of (R,R)-(+)-tartaric acid with triethoxyphenylsilane and triethylamine in ethanol. The structure of this optically active pentacoordinate phenyl-silicate consists of independent bis[(R,R)-tartrato]diphenyldisilicate anions and triethylammonium cations. In the crystal, the two Si atoms are five-coordinate and the geometry of each of the Si atoms is distorted from a trigonal bipyramid towards a square pyramid along the Berry pseudorotational coordinate by ca 9.8 and 8.9%, respectively. |
| 语种 | 英语 |
| WOS记录号 | WOS:A1996WE59400097 |
| 出版者 | MUNKSGAARD INT PUBL LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/44585]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, ZG |
| 推荐引用方式 GB/T 7714 | Wang, ZG,Liu, SG,Wang, D,et al. An optically active pentacoordinate silicate: (+)-bis(triethylammonium) bis-[(R,R)-tartrato(4-)]diphenyldisilicate[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS,1996,52:3179-3181. |
| APA | Wang, ZG,Liu, SG,Wang, D,&Sui, XM.(1996).An optically active pentacoordinate silicate: (+)-bis(triethylammonium) bis-[(R,R)-tartrato(4-)]diphenyldisilicate.ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS,52,3179-3181. |
| MLA | Wang, ZG,et al."An optically active pentacoordinate silicate: (+)-bis(triethylammonium) bis-[(R,R)-tartrato(4-)]diphenyldisilicate".ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 52(1996):3179-3181. |
入库方式： OAI收割
来源：化学研究所
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