Kinetic studies on vapor phase carbonylation of methanol to acetic acid over Rh/Ys catalyst
文献类型：期刊论文
| 作者 | Liu, ZY; Pan, PL; Zhu, CC; Yuan, GQ |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 1997-02-01 |
| 卷号 | 40期号:1页码:45-52 |
| 关键词 | Methanol Carbonylation Acetic Acid Kinetics |
| ISSN号 | 1001-652X |
| 英文摘要 | A novel catalyst Rh/Ys for the carbonylation of methanol to acetic acid with CH3I as the promoter shows excellent activity and selectivity. The reaction is kinetically controlled. The reaction rate is in proportion to the concentration of Rh and CH3I but has nothing to do with those of CH3OH and CO. The surface active energy is E(a) = 51.02 kJ/mol. A mechanism is also proposed. |
| 语种 | 英语 |
| WOS记录号 | WOS:A1997WJ36900007 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/44685]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | Liu, ZY,Pan, PL,Zhu, CC,et al. Kinetic studies on vapor phase carbonylation of methanol to acetic acid over Rh/Ys catalyst[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1997,40(1):45-52. |
| APA | Liu, ZY,Pan, PL,Zhu, CC,&Yuan, GQ.(1997).Kinetic studies on vapor phase carbonylation of methanol to acetic acid over Rh/Ys catalyst.SCIENCE IN CHINA SERIES B-CHEMISTRY,40(1),45-52. |
| MLA | Liu, ZY,et al."Kinetic studies on vapor phase carbonylation of methanol to acetic acid over Rh/Ys catalyst".SCIENCE IN CHINA SERIES B-CHEMISTRY 40.1(1997):45-52. |
入库方式： OAI收割
来源：化学研究所
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