Intramolecular substitutions of square planar rhodium(I) cationic complexes of cis-dicarbonyl nitrogen coordinated tridentate
文献类型：期刊论文
| 作者 | Yuan, GQ; Liu, ZY; Zhu, CC; Pan, PL; Liu, SH |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 1997-02-01 |
| 卷号 | 40期号:1页码:92-97 |
| 关键词 | Complex Square Planar Intramolecular Substitution |
| ISSN号 | 1001-652X |
| 英文摘要 | Four kinds of square planar cis-dicarbonyl-N, N-bis(1-pyridylethyl)-p-substituted-phenylamino rhodium(I) are reported. The changes of their structures were analyzed by XPS, IR and NMR spectroscopy. The results show that the weak N-->Rh coordinated bond can replace very soon the strong Rh-C pi back donation bond to form tris-nitrogen coordinated complexes due to the steric effect when the temperature is over 50 degrees C. This reaction is reversible. The his-nitrogen coordinated structure of the complex recovered when put under the atmosphere of CO. |
| 语种 | 英语 |
| WOS记录号 | WOS:A1997WJ36900012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/44839]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, GQ |
| 推荐引用方式 GB/T 7714 | Yuan, GQ,Liu, ZY,Zhu, CC,et al. Intramolecular substitutions of square planar rhodium(I) cationic complexes of cis-dicarbonyl nitrogen coordinated tridentate[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1997,40(1):92-97. |
| APA | Yuan, GQ,Liu, ZY,Zhu, CC,Pan, PL,&Liu, SH.(1997).Intramolecular substitutions of square planar rhodium(I) cationic complexes of cis-dicarbonyl nitrogen coordinated tridentate.SCIENCE IN CHINA SERIES B-CHEMISTRY,40(1),92-97. |
| MLA | Yuan, GQ,et al."Intramolecular substitutions of square planar rhodium(I) cationic complexes of cis-dicarbonyl nitrogen coordinated tridentate".SCIENCE IN CHINA SERIES B-CHEMISTRY 40.1(1997):92-97. |
入库方式： OAI收割
来源：化学研究所
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