Preparation and spectral properties of new molecular conductors based on anion salt
文献类型：期刊论文
| 作者 | Liu, SG; Liu, YQ; Zhu, DB |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 1997-09-01 |
| 卷号 | 89期号:3页码:187-191 |
| 关键词 | Photoelectron Spectroscopy Conductivity Organic COnductors Based On aniOn Salts |
| ISSN号 | 0379-6779 |
| 英文摘要 | Preparation, LR, W-Vis and X-ray photoelectron spectroscopy (XPS) of three molecular conductors derived from metal complexes of DMID ligand [TBA](0.6)[Ni(DMID)(2)], [TBA](0.44)[Ni(DMID)(2)] and TTF[TBA](0.35)[Ni(DMID)(2)](2) are reported (DMID = 1,3-dithiolene-2-one-4,5-dithiolate, TBA = tetrabutylammonium, TTF =tetrathiafulvalene). Electronic spectra show that the characteristic pi-electronic delocalization absorption band over the ligand through pi-d interactions in the complexes red-shifts with the increase of oxidization degree. In addition, XPS shows that there is a characteristic 'satellite' peak centered at around 168.7 eV, higher by about 4.7-5.4 eV than the main peak, in the S(2p) core-level region spectra of these partially oxidized or charge transfer conductive bisdithiolene metal complexes and, furthermore, the relative intensity of the 'satellite' peak increases with the oxidization degree of the complexes. (C) 1997 Elsevier Science S.A. |
| 语种 | 英语 |
| WOS记录号 | WOS:A1997YB07600005 |
| 出版者 | ELSEVIER SCIENCE SA LAUSANNE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/44877]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | Liu, SG,Liu, YQ,Zhu, DB. Preparation and spectral properties of new molecular conductors based on anion salt[J]. SYNTHETIC METALS,1997,89(3):187-191. |
| APA | Liu, SG,Liu, YQ,&Zhu, DB.(1997).Preparation and spectral properties of new molecular conductors based on anion salt.SYNTHETIC METALS,89(3),187-191. |
| MLA | Liu, SG,et al."Preparation and spectral properties of new molecular conductors based on anion salt".SYNTHETIC METALS 89.3(1997):187-191. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。