Polymerization of norbornene via an iron-based Complex/MAO catalytic system
文献类型：期刊论文
| 作者 | Mi, X; Ma, Z; Yan, WD; Liu, YX; Wang, H; Ke, YC; Hu, YL |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2002-11-01 |
| 卷号 | 18期号:4页码:462-465 |
| 关键词 | Polynorbornene Iron-based Complex Vinyl Addition Polymer Short-range Order Norbornene Polymerization |
| ISSN号 | 1005-9040 |
| 英文摘要 | Polynorbornenes were synthesized in the presence of an iron based catalyst, 2,6-bis[1-(2,6-diisopropyl-. phenylimino)ethyl]pyridine iron( II) dichloride. The FTIR, H-1 NMR and C-13 NMR analysis results revealed that the structure of the obtained. polynorbornenes consisted of vinyl addition polymer substructures without any ring-opening structures. The polymers were amorphous with a short-range order, displayed in the WAXD (wide angle X-ray diffraction) diagrams. The glass transition temperatures ranged from. 200 to 400 degreesC. The effects of the polymerization reaction conditions, such as Al/Fe molar ratio and toluene/CH2Cl2 volume ratio, tin the activity, intrinsic viscosity [eta] and T-g were also studied. |
| 语种 | 英语 |
| WOS记录号 | WOS:000179776200023 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/44911]  |
| 专题 | 中国科学院化学研究所 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Engn Plast, CNPC Key Lab Catalysis, Beijing Lab Catalysis,Ctr Mol Sci,Inst Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Hebei Univ Technol, Inst Polymer Sci & Engn, Tianjin 300130, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mi, X,Ma, Z,Yan, WD,et al. Polymerization of norbornene via an iron-based Complex/MAO catalytic system[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2002,18(4):462-465. |
| APA | Mi, X.,Ma, Z.,Yan, WD.,Liu, YX.,Wang, H.,...&Hu, YL.(2002).Polymerization of norbornene via an iron-based Complex/MAO catalytic system.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,18(4),462-465. |
| MLA | Mi, X,et al."Polymerization of norbornene via an iron-based Complex/MAO catalytic system".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 18.4(2002):462-465. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。