Fe-Promoted Chlorobenzylation of Terminal Alkynes through Benzylic C(sp(3))-H Bond Functionalization
文献类型：期刊论文
| 作者 | Shi, Jiang-Ling1; Zhang, Ji-Cheng2,3; Wang, Bi-Qn1; Hu, Ping1; Zhao, Ke-Qing1; Shi, Zhang-Jie2,3,4 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-03-18 |
| 卷号 | 18期号:6页码:1238-1241 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.5b02472 |
| 英文摘要 | A chlorobenzylation of terminal alkynes through Fe(II)promoted benzylic C(sp3) H bond functionalization in the presence of NCS as a chloride source was developed. Compared with previous methods to prepare polysubstituted alkenyl halides, the presented procedure provides an efficient alternative with high atom and step economy under mild conditions. The transformation was established to proceed through a single -electron transfer (SET) process with benzyl cations as key intermediates. |
| 语种 | 英语 |
| WOS记录号 | WOS:000372664600006 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/44933]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Bi-Qn; Shi, Zhang-Jie |
| 作者单位 | 1.Sichuan Normal Univ, Coll Chem & Mat Chem, Chengdu 610066, Sichuan, Peoples R China 2.Peking Univ, BNLMS, Beijing 100871, Peoples R China 3.Peking Univ, Minist Educ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 4.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Jiang-Ling,Zhang, Ji-Cheng,Wang, Bi-Qn,et al. Fe-Promoted Chlorobenzylation of Terminal Alkynes through Benzylic C(sp(3))-H Bond Functionalization[J]. ORGANIC LETTERS,2016,18(6):1238-1241. |
| APA | Shi, Jiang-Ling,Zhang, Ji-Cheng,Wang, Bi-Qn,Hu, Ping,Zhao, Ke-Qing,&Shi, Zhang-Jie.(2016).Fe-Promoted Chlorobenzylation of Terminal Alkynes through Benzylic C(sp(3))-H Bond Functionalization.ORGANIC LETTERS,18(6),1238-1241. |
| MLA | Shi, Jiang-Ling,et al."Fe-Promoted Chlorobenzylation of Terminal Alkynes through Benzylic C(sp(3))-H Bond Functionalization".ORGANIC LETTERS 18.6(2016):1238-1241. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。