中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Zinc-Catalyzed Hydrosilylation Copolymerization of Aromatic Dialdehydes with Diphenylsilane

文献类型:期刊论文

作者Li, Chuanyang1,2; Hua, Xiufang1,2; Mou, Zehuai1; Liu, Xinli1; Cui, Dongmei1
刊名MACROMOLECULAR RAPID COMMUNICATIONS
出版日期2017-11-01
卷号38期号:22
关键词Aldehydes Phenylsilane Step-growth Polymerization Zinc Hydride
ISSN号1022-1336
DOI10.1002/marc.201700590
英文摘要The hydrosilylation reaction of diphenylsilane and phthalaldehyde is catalyzed by heteroscorpionate zinc hydride complex LZnH (1, L = ((Me)Pz)(2)CP(Ph)(2)NPh, (Me)Pz = 3,5-dimethylpyrazolyl). Both terephthalaldehyde (tPAA) and isophthalaldehyde (iPAA) affords linear polymer; however, when PAA is used, a seven-membered cyclic silyl ether is formed. These products are characterized by H-1 and C-13 NMR spectra. Other properties of polymers are determined by gel permeation chromatography (GPC)-multiangle laser-light scattering, differential scanning calorimetry, and thermogravimetry.
语种英语
WOS记录号WOS:000417215700010
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/45139]  
专题中国科学院化学研究所
通讯作者Cui, Dongmei
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China
2.Univ Chinese Acad Sci, Changchun Branch, Changchun 130022, Jilin, Peoples R China
推荐引用方式
GB/T 7714
Li, Chuanyang,Hua, Xiufang,Mou, Zehuai,et al. Zinc-Catalyzed Hydrosilylation Copolymerization of Aromatic Dialdehydes with Diphenylsilane[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2017,38(22).
APA Li, Chuanyang,Hua, Xiufang,Mou, Zehuai,Liu, Xinli,&Cui, Dongmei.(2017).Zinc-Catalyzed Hydrosilylation Copolymerization of Aromatic Dialdehydes with Diphenylsilane.MACROMOLECULAR RAPID COMMUNICATIONS,38(22).
MLA Li, Chuanyang,et al."Zinc-Catalyzed Hydrosilylation Copolymerization of Aromatic Dialdehydes with Diphenylsilane".MACROMOLECULAR RAPID COMMUNICATIONS 38.22(2017).

入库方式: OAI收割

来源:化学研究所

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