A Molecular Barium Hydrido Complex Stabilized by a Super-Bulky Hydrotris(pyrazolyl)borate Ligand
文献类型：期刊论文
| 作者 | Shi, Xianghui1; Hou, Cuiping1,2; Zhou, Chulu1,2; Song, Yanyao1; Cheng, Jianhua1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-12-22 |
| 卷号 | 56期号:52页码:16650-16653 |
| ISSN号 | 1433-7851 |
| 关键词 | Alkaline-earth Metals Barium Hydride Butadiyne Carbon Monoxide Tris(Pyrazolyl)Borate |
| DOI | 10.1002/anie.201709344 |
| 英文摘要 | Hydrogenolysis of the scorpionate-supported barium alkyl complex (Tp(Ad,iPr))Ba[CH(SiMe3)(2)](THF) (Tp(Ad,iPr)=hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) afforded the dinuclear barium hydrido complex [(Tp(Ad,iPr))Ba(mu-H)](2) (2), which was characterized by NMR spectroscopy and single-crystal X-ray analysis. Exposure of 2 with 1 atm of CO resulted in a reductive coupling process to form the cis-ethendiolate dianion (3). Reaction of 2 with one equivalent of PhC equivalent to C-C equivalent to CPh gave barium 1,4-diphenyl-2-butyne-1,4-diyl complex {[(Tp(Ad,iPr))Ba](2)(PhCH-C equivalent to C-CHPh) (4). |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000418359400043 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45231]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cheng, Jianhua |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Changchun Branch, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Xianghui,Hou, Cuiping,Zhou, Chulu,et al. A Molecular Barium Hydrido Complex Stabilized by a Super-Bulky Hydrotris(pyrazolyl)borate Ligand[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(52):16650-16653. |
| APA | Shi, Xianghui,Hou, Cuiping,Zhou, Chulu,Song, Yanyao,&Cheng, Jianhua.(2017).A Molecular Barium Hydrido Complex Stabilized by a Super-Bulky Hydrotris(pyrazolyl)borate Ligand.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(52),16650-16653. |
| MLA | Shi, Xianghui,et al."A Molecular Barium Hydrido Complex Stabilized by a Super-Bulky Hydrotris(pyrazolyl)borate Ligand".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.52(2017):16650-16653. |
入库方式： OAI收割
来源：化学研究所
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