Aerobic C-C Bond Cleavage of Indoles by Visible-Light Photoredox Catalysis with Ru(bpy)(3)(2+)
文献类型：期刊论文
| 作者 | Ji, Xiaochen1; Li, Dongdong1; Wang, Zhongzhen1; Tan, Muyun1; Huang, Huawen1; Deng, Guo-Jun1,2,3 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2017-12-08 |
| 期号 | 45页码:6652-6659 |
| 关键词 | Photoredox Catalysis Photochemistry Ruthenium Cleavage Reactions Oxygenation Radicals |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201701245 |
| 英文摘要 | Photoredox catalysis with Ru(bpy)(3)(2+) (2,2-bipyridine) has been used to enable the activation of oxygen in the aerobic C-C cleavage/oxygenation reaction of indoles. A number of indole substrates that contain various functional groups were successfully employed in the reaction to give a wide range of ortho-aminobenzaldehyde derivatives. These products can then be used as versatile building blocks for further synthetic modifications. Mechanistic studies suggest that the reaction proceeds through a radical pathway. |
| 语种 | 英语 |
| WOS记录号 | WOS:000417760100012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45281]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ji, Xiaochen; Huang, Huawen |
| 作者单位 | 1.Xiangtan Univ, Coll Chem, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Xiaochen,Li, Dongdong,Wang, Zhongzhen,et al. Aerobic C-C Bond Cleavage of Indoles by Visible-Light Photoredox Catalysis with Ru(bpy)(3)(2+)[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2017(45):6652-6659. |
| APA | Ji, Xiaochen,Li, Dongdong,Wang, Zhongzhen,Tan, Muyun,Huang, Huawen,&Deng, Guo-Jun.(2017).Aerobic C-C Bond Cleavage of Indoles by Visible-Light Photoredox Catalysis with Ru(bpy)(3)(2+).EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(45),6652-6659. |
| MLA | Ji, Xiaochen,et al."Aerobic C-C Bond Cleavage of Indoles by Visible-Light Photoredox Catalysis with Ru(bpy)(3)(2+)".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .45(2017):6652-6659. |
入库方式： OAI收割
来源：化学研究所
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