Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes
文献类型：期刊论文
| 作者 | Zhou, Qi1,2; Li, Shichao1,2; Zhang, Yan1,2; Wang, Jianbo1,2,3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-12-11 |
| 卷号 | 56期号:50页码:16013-16017 |
| 关键词 | Diazo Compounds Indenes Insertion Metal Carbenes N-tosylhydrazones |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201709375 |
| 英文摘要 | A rhodium(II)- or copper(I)-catalyzed formal intramolecular carbene insertion into vinylic C(sp(2))-H bonds is reported herein. This method provides straightforward access to 1H-indenes with high efficiency and excellent functional-group compatibility. Mechanistically, the reaction is proposed to involve the following sequence: metal carbene formation, intramolecular nucleophilic addition of the double bond to the electron-deficient carbene carbon atom, dearomatization, and finally a 1,5-H shift. |
| 语种 | 英语 |
| WOS记录号 | WOS:000417200600039 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45301]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Qi,Li, Shichao,Zhang, Yan,et al. Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(50):16013-16017. |
| APA | Zhou, Qi,Li, Shichao,Zhang, Yan,&Wang, Jianbo.(2017).Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(50),16013-16017. |
| MLA | Zhou, Qi,et al."Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp(2))-H Bonds: Access to Substituted 1H-Indenes".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.50(2017):16013-16017. |
入库方式： OAI收割
来源：化学研究所
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