A novel mixed-metal borate with large [B12O18(OH)(6)](6-) motif: Synthesis, structure and property
文献类型：期刊论文
| 作者 | Wei, Li1; Pan, Jie1; Xue, Zhen-Zhen1; Wang, Guo-Ming1; Wang, Ying-Xia2 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2018 |
| 卷号 | 75页码:9-13 |
| 关键词 | Metal Borate Cluster Crystal Structure Solvothermal Synthesis |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2017.11.004 |
| 英文摘要 | A new mixed-metal polyborate, Na5Li[B12O18(OH)(6)]center dot 2H(2)O (1), has been synthesized using solvothermal method and characterized by IR spectroscopy, thermogravimetric analysis, UVeVis spectroscopy, powder and single-crystal X-ray diffraction, respectively. It crystallizes in the trigonal space group R-3c (No. 167) with unit cell parameters of a = b = 9.6767(6) angstrom, c = 36.358(5) angstrom, and Z = 6. Its structure features unprecedented 3D framework constructed from novel honeycomb-shaped inorganic Na-O sheets with unique 12-MR sodium rings and supramolecular polyborate 2D layers of lithium-centered [B12O18(OH)(6)](6-). UVeVis spectral characterization indicates that compound 1 is a wide-band-gap semiconductor. (C) 2017 Elsevier Masson SAS. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000418566200002 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45331]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Li,Pan, Jie,Xue, Zhen-Zhen,et al. A novel mixed-metal borate with large [B12O18(OH)(6)](6-) motif: Synthesis, structure and property[J]. SOLID STATE SCIENCES,2018,75:9-13. |
| APA | Wei, Li,Pan, Jie,Xue, Zhen-Zhen,Wang, Guo-Ming,&Wang, Ying-Xia.(2018).A novel mixed-metal borate with large [B12O18(OH)(6)](6-) motif: Synthesis, structure and property.SOLID STATE SCIENCES,75,9-13. |
| MLA | Wei, Li,et al."A novel mixed-metal borate with large [B12O18(OH)(6)](6-) motif: Synthesis, structure and property".SOLID STATE SCIENCES 75(2018):9-13. |
入库方式： OAI收割
来源：化学研究所
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