Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems
文献类型：期刊论文
| 作者 | Song, Zehua1; Lv, Xiaolin2; Gao, Longcheng1; Jiang, Lei1,3 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2018-01-07 |
| 卷号 | 6期号:1页码:171-177 |
| ISSN号 | 2050-7526 |
| DOI | 10.1039/c7tc04771a |
| 英文摘要 | A block copolymer (BCP) and a polymer blend containing small amounts of fluorogenic molecules with aggregation-induced emission (AIE) characteristics exhibited dramatic differences in the fluorescence properties. In particular, AIEgens with different polarities were doped in BCP polystyrene-b-polylactide (PS-b-PLA) and the PS/PLA blend. For the BCP, whether the AIEgens were selectively located in one phase or not, the intramolecular motions of the phenyl rings in AIEgens were affected by both the PS and PLA segment motions, due to the covalent bonds between the constitutive blocks. Therefore, the fluorescence was affected by the segment movements of PS and PLA. In contrast, the AIEgen-doped polymer blend exhibited location dependent fluorescence. The fluorescence was affected by the segment movements where the AIEgens were located, because there were no connections between the PS and PLA chains. This visualization method will provide new insights into monitoring the chain motions of macromolecules with more complex structures. |
| 语种 | 英语 |
| WOS记录号 | WOS:000418620900019 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45361]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, Longcheng |
| 作者单位 | 1.Beihang Univ, Sch Chem & Environm, Key Lab Beijing Energy, Minist Educ,Lab Bioinspired Smart Interfacial Sci, Beijing 100191, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Bioinspired Mat & Interfacial Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Zehua,Lv, Xiaolin,Gao, Longcheng,et al. Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems[J]. JOURNAL OF MATERIALS CHEMISTRY C,2018,6(1):171-177. |
| APA | Song, Zehua,Lv, Xiaolin,Gao, Longcheng,&Jiang, Lei.(2018).Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems.JOURNAL OF MATERIALS CHEMISTRY C,6(1),171-177. |
| MLA | Song, Zehua,et al."Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems".JOURNAL OF MATERIALS CHEMISTRY C 6.1(2018):171-177. |
入库方式： OAI收割
来源：化学研究所
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