Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand
文献类型：期刊论文
| 作者 | Zhou, Zishuo1; Xin, Nana1; Gan, Liangbing1,2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2018-01-09 |
| 卷号 | 24期号:2页码:451-457 |
| 关键词 | Fullerene Ligand Metal Complex Open-cage Peroxide |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201704517 |
| 英文摘要 | An open-cage C-60 derivative 9 with anilino, hemiketal, and lactone moieties on the edge of the opening was prepared through a fullerene-mixed peroxide procedure. Key steps include decarbonylation, intramolecular Friedel-Crafts reaction and oxetane ring opening rearrangement. The open-cage compound9 readily reacts with various metal salts. A nickel complex was obtained by treating 9 with NiCl2 at r.t. followed by purification on a silica gel column. Single-crystal X-ray diffraction analysis showed that the nickel ion is coordinated to two ligands with an octahedral geometry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000419623600025 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45373]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Minist Educ,Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Zishuo,Xin, Nana,Gan, Liangbing. Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(2):451-457. |
| APA | Zhou, Zishuo,Xin, Nana,&Gan, Liangbing.(2018).Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand.CHEMISTRY-A EUROPEAN JOURNAL,24(2),451-457. |
| MLA | Zhou, Zishuo,et al."Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand".CHEMISTRY-A EUROPEAN JOURNAL 24.2(2018):451-457. |
入库方式： OAI收割
来源：化学研究所
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