Self-Assembly-Triggered Cis-to-Trans Conversion of Azobenzene Compounds
文献类型：期刊论文
| 作者 | Wu, Zheng1; Xue, Rongrong1; Xie, Mengqi1; Wang, Xuejiao1; Liu, Zihao1; Drechsler, Markus2; Huang, Jianbin1; Yan, Yun1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY LETTERS
 |
| 出版日期 | 2018-01-04 |
| 卷号 | 9期号:1页码:163-169 |
| ISSN号 | 1948-7185 |
| DOI | 10.1021/acs.jpclett.7b03060 |
| 英文摘要 | Cis-to-trans transition of azobenzene compounds usually occurs under appropriate light irradiation or slow thermal relaxation, and one can hardly obtain complete cis-to-trans transition of azos due to the overlap of the n-pi* transition of the trans and the cis isomers. We show that by viewing the photostationary state as a chemical equilibrium between the cis and trans isomers, triggered self-assembly of the trans isomers can promote the cis-to-trans transition, and trans azos with spectrum-grade purity can even be achieved using an elegantly designed coordinating azo. This work establishes a new paradigm for manipulating the cis-to-trans transition of azo compounds, which may inspire designs for various azo-based advanced materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000419750900027 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45405]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Yun |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China 2.Univ Bayreuth, BPI, Key Lab Electron & Opt Microscopy, Univ Str 30, D-95440 Bayreuth, Germany |
| 推荐引用方式 GB/T 7714 | Wu, Zheng,Xue, Rongrong,Xie, Mengqi,et al. Self-Assembly-Triggered Cis-to-Trans Conversion of Azobenzene Compounds[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2018,9(1):163-169. |
| APA | Wu, Zheng.,Xue, Rongrong.,Xie, Mengqi.,Wang, Xuejiao.,Liu, Zihao.,...&Yan, Yun.(2018).Self-Assembly-Triggered Cis-to-Trans Conversion of Azobenzene Compounds.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,9(1),163-169. |
| MLA | Wu, Zheng,et al."Self-Assembly-Triggered Cis-to-Trans Conversion of Azobenzene Compounds".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 9.1(2018):163-169. |
入库方式： OAI收割
来源：化学研究所
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