Copper-catalyzed synthesis of benzanilides from lignin model substrates 2-phenoxyacetophenones under an air atmosphere
文献类型：期刊论文
| 作者 | Liu, Xinwei1,2; Zhang, Hongye1; Wu, Cailing1,2; Liu, Zhenghui1,2; Chen, Yu1,2; Yu, Bo1; Liu, Zhimin1,2 |
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2018-01-21 |
| 卷号 | 42期号:2页码:1223-1227 |
| ISSN号 | 1144-0546 |
| DOI | 10.1039/c7nj02589k |
| 英文摘要 | The synthesis of chemicals from biomass-derived compounds is an interesting and challenging topic. In this work, using the lignin-derived 2-phenoxyacetophenones as the feedstock we present a novel approach for the synthesis of benzanilides via the reaction of 2-phenoxyacetophenones with anilines catalyzed by CuCl2 in DMSO at 120 degrees C under an air atmosphere. This approach has wide scope for 2-phenoxyacetophenones and anilines, and various benzanilides accompanied by the corresponding phenols could be obtained in high yields via changing the 2-phenoxyacetophenones and anilines. The reaction mechanism study indicated that the oxidative cleavage of the C-C bond in 2-phenoxyacetophenones and the formation of a C-N bond occurred simultaneously in the reaction process, resulting in the formation of benzanilides together with phenols. |
| 语种 | 英语 |
| WOS记录号 | WOS:000419994300056 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45411]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Zhimin |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Thermodynam, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xinwei,Zhang, Hongye,Wu, Cailing,et al. Copper-catalyzed synthesis of benzanilides from lignin model substrates 2-phenoxyacetophenones under an air atmosphere[J]. NEW JOURNAL OF CHEMISTRY,2018,42(2):1223-1227. |
| APA | Liu, Xinwei.,Zhang, Hongye.,Wu, Cailing.,Liu, Zhenghui.,Chen, Yu.,...&Liu, Zhimin.(2018).Copper-catalyzed synthesis of benzanilides from lignin model substrates 2-phenoxyacetophenones under an air atmosphere.NEW JOURNAL OF CHEMISTRY,42(2),1223-1227. |
| MLA | Liu, Xinwei,et al."Copper-catalyzed synthesis of benzanilides from lignin model substrates 2-phenoxyacetophenones under an air atmosphere".NEW JOURNAL OF CHEMISTRY 42.2(2018):1223-1227. |
入库方式： OAI收割
来源：化学研究所
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