Design and Application of a High-Temperature Linear Ion Trap Reactor
文献类型：期刊论文
| 作者 | Jiang, Li-Xue1,2; Liu, Qing-Yu1,2; Li, Xiao-Na1; He, Sheng-Gui1,2 |
| 刊名 | JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
 |
| 出版日期 | 2018 |
| 卷号 | 29期号:1页码:78-84 |
| 关键词 | Ion-molecule Reactions Mass Spectrometry Ion Trap Co Oxidation Variable Temperature Density Functional Theory |
| ISSN号 | 1044-0305 |
| DOI | 10.1007/s13361-017-1828-3 |
| 英文摘要 | A high-temperature linear ion trap reactor with hexapole design was homemade to study ion-molecule reactions at variable temperatures. The highest temperature for the trapped ions is up to 773 K, which is much higher than those in available reports. The reaction between V2O6 (-) cluster anions and CO at different temperatures was investigated to evaluate the performance of this reactor. The apparent activation energy was determined to be 0.10 +/- 0.02 eV, which is consistent with the barrier of 0.12 eV calculated by density functional theory. This indicates that the current experimental apparatus is prospective to study ion-molecule reactions at variable temperatures, and more kinetic details can be obtained to have a better understanding of chemical reactions that have overall barriers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000423390800010 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45483]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Xiao-Na; He, Sheng-Gui |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Li-Xue,Liu, Qing-Yu,Li, Xiao-Na,et al. Design and Application of a High-Temperature Linear Ion Trap Reactor[J]. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,2018,29(1):78-84. |
| APA | Jiang, Li-Xue,Liu, Qing-Yu,Li, Xiao-Na,&He, Sheng-Gui.(2018).Design and Application of a High-Temperature Linear Ion Trap Reactor.JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,29(1),78-84. |
| MLA | Jiang, Li-Xue,et al."Design and Application of a High-Temperature Linear Ion Trap Reactor".JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY 29.1(2018):78-84. |
入库方式： OAI收割
来源：化学研究所
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