Microwave assisted synthesis of glycerol carbonate from glycerol and urea
文献类型：期刊论文
| 作者 | Zhang, Lujun1,2; Zhang, Zhaofu1; Wu, Congyi1; Qian, Qingli1; Ma, Jun1; Jiang, Long1; Han, Buxing1,2 |
| 刊名 | PURE AND APPLIED CHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 90期号:1页码:1-6 |
| 关键词 | Glycerol Glycerol Carbonate Glycerolysis Icgc-6 Microwave Urea |
| ISSN号 | 0033-4545 |
| DOI | 10.1515/pac-2017-0303 |
| 英文摘要 | The transformation of glycerol into value-added chemicals is an interesting topic in Green Chemistry. The glycerolysis of urea into glycerol carbonate is an important route of glycerol transformation. In this work, the synthesis of glycerol carbonate from glycerol and urea was performed under microwave irradiation and solvent free conditions. The catalytic properties of ZnSO4, ZnCl2, CuSO4 and MgSO4 were tested and ZnSO4 showed the best performance. The effects of catalyst amount, temperature, reaction time, microwave power, molar ratio of urea to glycerol on the reaction were studied using ZnSO4 as the catalyst. It was demonstrated that microwave irradiation could promote the reaction effectively, and the yield of desired product glycerol carbonate could reach 93.7 %. |
| 语种 | 英语 |
| WOS记录号 | WOS:000426360200001 |
| 出版者 | WALTER DE GRUYTER GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45643]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Zhaofu; Han, Buxing |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Colloid & Interface & Chem Thermodynam, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Lujun,Zhang, Zhaofu,Wu, Congyi,et al. Microwave assisted synthesis of glycerol carbonate from glycerol and urea[J]. PURE AND APPLIED CHEMISTRY,2018,90(1):1-6. |
| APA | Zhang, Lujun.,Zhang, Zhaofu.,Wu, Congyi.,Qian, Qingli.,Ma, Jun.,...&Han, Buxing.(2018).Microwave assisted synthesis of glycerol carbonate from glycerol and urea.PURE AND APPLIED CHEMISTRY,90(1),1-6. |
| MLA | Zhang, Lujun,et al."Microwave assisted synthesis of glycerol carbonate from glycerol and urea".PURE AND APPLIED CHEMISTRY 90.1(2018):1-6. |
入库方式： OAI收割
来源：化学研究所
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