Preparation of an efficient Fe/N/C electrocatalyst and its application for oxygen reduction reaction in alkaline media
文献类型：期刊论文
| 作者 | Wang, Chunxia1; Yang, Fan1; Qiu, Tian1; Cao, Yan1; Zhong, Huangliang1; Yu, Changchun1; Li, Ranjia1; Mao, Lanqun2; Li, Yongfeng1 |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2018-02-01 |
| 卷号 | 810页码:62-68 |
| 关键词 | Fe/n/c Electrocatalyst Oxygen Reduction Reaction Porous Carbon Nanomaterial |
| ISSN号 | 1572-6657 |
| DOI | 10.1016/j.jelechem.2017.12.084 |
| 英文摘要 | We demonstrate a highly efficient Fe/N/C electrocatalyst for oxygen reduction reaction (ORR) which was prepared through MgO template directed approach followed by pyrolysis of iron salt and nitrogen-rich carbon precursors. The Fe/N/C electrocatalyst displays a porous carbon structure with iron atoms, Fe3C nanoparticles and Fe-N-x as active sites which endow the electrocatalyst with plenty of accessible and active sites that are favorable for the enhanced electrocatalytic activity towards ORR. The as-obtained Fe/N/C electrocatalyst exhibits excellent electrocatalytic performance for ORR matching those of the state-of-the-art commercial Pt/C with a higher catalytic activity via a four-electron transfer process, a comparable onset and half-wave potentials, and a peroxide yield lower than 10% in alkaline media. Besides, the Fe/N/C electrocatalyst displays a higher durability and negligible methanol-crossover effect compared with Pt/C electrocatalyst. |
| 语种 | 英语 |
| WOS记录号 | WOS:000425560800009 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45701]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Fan; Li, Yongfeng |
| 作者单位 | 1.China Univ Petr, State Key Lab Heavy Oil Proc, Inst New Energy, Beijing 102249, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Analyt Chem Living Biosyst, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chunxia,Yang, Fan,Qiu, Tian,et al. Preparation of an efficient Fe/N/C electrocatalyst and its application for oxygen reduction reaction in alkaline media[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2018,810:62-68. |
| APA | Wang, Chunxia.,Yang, Fan.,Qiu, Tian.,Cao, Yan.,Zhong, Huangliang.,...&Li, Yongfeng.(2018).Preparation of an efficient Fe/N/C electrocatalyst and its application for oxygen reduction reaction in alkaline media.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,810,62-68. |
| MLA | Wang, Chunxia,et al."Preparation of an efficient Fe/N/C electrocatalyst and its application for oxygen reduction reaction in alkaline media".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 810(2018):62-68. |
入库方式： OAI收割
来源：化学研究所
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