Efficient and Mild Transfer Hydrogenolytic Cleavage of Aromatic Ether Bonds in Lignin-Derived Compounds over Ru/C
文献类型：期刊论文
| 作者 | Wu, Haoran1,2; Song, Jinliang1; Xie, Chao1,2; Wu, Congyi1; Chen, Chunjun1,2; Han, Buxing1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 6期号:3页码:2872-2877 |
| 关键词 | Lignin-derived Compounds Aromatic Ether Bonds Transfer Hydrogenolytic Cleavage Biomass Conversion Isopropanol |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.7b02993 |
| 英文摘要 | Cleavage of aromatic ether bonds is crucial for the valorization of lignin and its fragments, which is challenging under mild conditions because the bonds are very stable. Herein, we found that Ru/C could efficiently catalyze the cleavage of the aromatic ether bonds in various lignin-derived compounds via a transfer hydrogenolytic route using isopropanol as the hydrogen resource. Various lignin derived compounds could be efficiently cleaved over commercial Ru/C to generate the corresponding aliphatic alkanes, aliphatic alcohols and aromatic derivatives under milder conditions. A mechanism study indicated that the reaction occurred through the direct cleavage of aromatic ether bonds or the formation of the reaction phenyl ether. |
| 语种 | 英语 |
| WOS记录号 | WOS:000427092900006 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45759]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Song, Jinliang; Han, Buxing |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, 2 Zhongguancun North First St, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Haoran,Song, Jinliang,Xie, Chao,et al. Efficient and Mild Transfer Hydrogenolytic Cleavage of Aromatic Ether Bonds in Lignin-Derived Compounds over Ru/C[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(3):2872-2877. |
| APA | Wu, Haoran,Song, Jinliang,Xie, Chao,Wu, Congyi,Chen, Chunjun,&Han, Buxing.(2018).Efficient and Mild Transfer Hydrogenolytic Cleavage of Aromatic Ether Bonds in Lignin-Derived Compounds over Ru/C.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(3),2872-2877. |
| MLA | Wu, Haoran,et al."Efficient and Mild Transfer Hydrogenolytic Cleavage of Aromatic Ether Bonds in Lignin-Derived Compounds over Ru/C".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.3(2018):2872-2877. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。