中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Micro/macro-stress relationship and local stress distribution in polyethylene spherulites upon uniaxial stretching in the small strain domain

文献类型:期刊论文

作者Xiong, Bijin1; Lame, Olivier2; Seguela, Roland2; Men, Yongfeng1
刊名POLYMER
出版日期2018-03-28
卷号140页码:215-224
关键词Polyethylene Spherulites Stress Triaxiality
ISSN号0032-3861
DOI10.1016/j.polymer.2018.02.052
英文摘要Local stress of polyethylene spherulites under uniaxial stretching in small strain domain has been investigated by in-situ wide angle X-ray diffraction (WAXD) in comparison with macroscopic stress. Particular attention is paid to the elastic strain range. The local stress in equatorial and polar regions both increase in absolute value and follow a linear relation versus macroscopic stress. However, local stress turns out to be heterogeneous over the whole spherulites volume. The polar region shows higher local stress than equatorial region. Moreover, local stress along the a and b crystallographic axes in the crystalline lamellae enable determining the local stress triaxiality which is heterogenous. The increase of crystallinity promotes stress distribution heterogeneity throughout the spherulites. The origin of these phenomenon are discussed in terms of crystalline network percolation and effect of amorphous layer that modifies the local mechanical behavior. The present study provides a useful means for achieving the scale transition between the micro and the macro structural levels that is necessary for the modeling of the mechanical behavior of semi-crystalline polymers via micromechanical approaches. (C) 2018 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000428029700024
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/45805]  
专题中国科学院化学研究所
通讯作者Lame, Olivier; Men, Yongfeng
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Renmin St 5625, Changchun 130022, Jilin, Peoples R China
2.INSA Lyon CNRS UMR 5510, MATEIS, LyonTech La Doua, Blaise Pascal Bldg, F-69621 Villeurbanne, France
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GB/T 7714
Xiong, Bijin,Lame, Olivier,Seguela, Roland,et al. Micro/macro-stress relationship and local stress distribution in polyethylene spherulites upon uniaxial stretching in the small strain domain[J]. POLYMER,2018,140:215-224.
APA Xiong, Bijin,Lame, Olivier,Seguela, Roland,&Men, Yongfeng.(2018).Micro/macro-stress relationship and local stress distribution in polyethylene spherulites upon uniaxial stretching in the small strain domain.POLYMER,140,215-224.
MLA Xiong, Bijin,et al."Micro/macro-stress relationship and local stress distribution in polyethylene spherulites upon uniaxial stretching in the small strain domain".POLYMER 140(2018):215-224.

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来源:化学研究所

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