Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-
文献类型：期刊论文
| 作者 | Wang, Li-Na1,3,4; Li, Xiao-Na1,4; Jiang, Li-Xue1,3,4; Yang, Bin2,3,4; Liu, Qing-Yu1,4; Xu, Hong-Guang2,4; Zheng, Wei-Jun2,4; He, Sheng-Gui1,3,4 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-03-19 |
| 卷号 | 57期号:13页码:3349-3353 |
| 关键词 | Carbon Monoxide Copper Heterogeneous Catalysis Mass Spectrometry Vanadium |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201712129 |
| 英文摘要 | Catalytic CO oxidation by molecular O-2 is an important model reaction in both the condensed phase and gas-phase studies. Available gas-phase studies indicate that noble metal is indispensable in catalytic CO oxidation by O-2 under thermal collision conditions. Herein, we identified the first example of noble-metal-free heteronuclear oxide cluster catalysts, the copper-vanadium bimetallic oxide clusters Cu2VO3-5- for CO oxidation by O-2. The reactions were characterized by mass spectrometry, photoelectron spectroscopy, and density functional calculations. The dynamic nature of the Cu-Cu unit in terms of the electron storage and release is the driving force to promote CO oxidation and O-2 activation during the catalysis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000427235600010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45811]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Xiao-Na; Zheng, Wei-Jun; He, Sheng-Gui |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Wang, Li-Na,Li, Xiao-Na,Jiang, Li-Xue,et al. Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3 |
| APA | Wang, Li-Na.,Li, Xiao-Na.,Jiang, Li-Xue.,Yang, Bin.,Liu, Qing-Yu.,...&He, Sheng-Gui.(2018).Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(13),3349-3353. |
| MLA | Wang, Li-Na,et al."Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.13(2018):3349-3353. |
入库方式： OAI收割
来源：化学研究所
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