Reversible Thermal-Induced Fluorescence Color Change of Tetraphenylethylene-Labeled Nylon-6
文献类型：期刊论文
| 作者 | Xu, Jiaru1,2; Ji, Wenxi3; Li, Chao1; Lv, Yufeng1; Qiu, Zijie4,5; Gao, Longcheng1; Chen, Erqiang2; Lam, Jacky W. Y.4,5; Tang, Benzhong4,5; Jiang, Lei1 |
| 刊名 | ADVANCED OPTICAL MATERIALS
 |
| 出版日期 | 2018-03-19 |
| 卷号 | 6期号:6 |
| ISSN号 | 2195-1071 |
| 关键词 | Fluorescence Nylon-6 Tetraphenylethylene |
| DOI | 10.1002/adom.201701149 |
| 英文摘要 | Nylon is the first synthetic fiber material and is widely used throughout the world. However, traditional nylons show limited optical applications as they emit no or weak fluorescence. Herein, a fluorescent nylon-6 is synthesized by utilizing tetraphenylethylene (TPE) carrying two amino groups as coinitiator. The resulting TPE-labeled nylon-6 exhibits reversible thermal-induced fluorescence color change. This unique property arises from the synergistic effect of its chemical structure and conformation. The thermal expansion of the polymer at high temperature induces the phenyl rings of TPE to rotate in a greater extent, which decreases the conjugation of TPE to lead to a blueshift in its fluorescence. The novel fluorescence property of TPE-labeled nylon-6 enables it to find applications in fields like chemosensor and security label. |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000428348200008 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45879]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, Longcheng |
| 作者单位 | 1.Beihang Univ, Beijing Key Lab Bioinspired Energy Mat & Devices, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ,Sch Chem, Beijing 100191, Peoples R China 2.Peking Univ, Ctr Soft Matter Sci & Engn, Key Lab Polymer Chem & Phys, Beijing Natl Lab Mol Sci,Coll Chem,Minist Educ, Beijing 100871, Peoples R China 3.China Petr & Chem Corp, Beijing Res Inst Chem Ind, Beijing 100013, Peoples R China 4.Hong Kong Univ Sci & Technol, Chinese Natl Engn Res Ctr, Ctr Tissue Restorat & Reconstruct,Hong Kong Branc, Inst Mol Funct Mat,State Key Lab Nanosci,Div Biom, Kowloon 999077, Hong Kong, Peoples R China 5.Hong Kong Univ Sci & Technol, Div Life Sci, Kowloon 999077, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Jiaru,Ji, Wenxi,Li, Chao,et al. Reversible Thermal-Induced Fluorescence Color Change of Tetraphenylethylene-Labeled Nylon-6[J]. ADVANCED OPTICAL MATERIALS,2018,6(6). |
| APA | Xu, Jiaru.,Ji, Wenxi.,Li, Chao.,Lv, Yufeng.,Qiu, Zijie.,...&Jiang, Lei.(2018).Reversible Thermal-Induced Fluorescence Color Change of Tetraphenylethylene-Labeled Nylon-6.ADVANCED OPTICAL MATERIALS,6(6). |
| MLA | Xu, Jiaru,et al."Reversible Thermal-Induced Fluorescence Color Change of Tetraphenylethylene-Labeled Nylon-6".ADVANCED OPTICAL MATERIALS 6.6(2018). |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。