The influence of nanocomposite pour point depressant on the crystallization of waxy oil
文献类型：期刊论文
| 作者 | Huang, Huirong1; Wang, Wei1,2,3; Peng, Zeheng2; Ding, Yanfen4; Li, Kai1; Li, Qingping5; Gong, Jing1,2,3 |
| 刊名 | FUEL
 |
| 出版日期 | 2018-06-01 |
| 卷号 | 221页码:257-268 |
| 关键词 | Pour Point Depressant Nanocomposite Wax Crystal Diffraction Intensity Interplanar Spacing |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2018.01.040 |
| 英文摘要 | Improving the fluidity of waxy oil with different pour point depressants (PPDs) at low temperature is of great technical and economic interest. In the present work, a nanocomposite pour point depressant (NPPD) which was developed based on melt blending of organically modified montmorillonite and ethylene/vinyl acetate (EVA) copolymer has been investigated systematically. The microscopic properties of waxy model oil with NPPD were investigated and compared with that of conventional EVA through X-ray diffraction. The interplanar spacing and lattice parameter are found to decrease in the (0 0 6) interplanar and z-axis for both NPPD and EVA, but display opposite trends between NPPD and EVA in (1 1 0), (2 0 0), x-axis. For NPPD, the wax appearance temperature (WAT) shows a slight increase with increasing concentration, while the crystallinity index (CI) accompanied with peak area in different crystal interplanar decreases. In EVA system, however, the WAT and CI present opposite trends. The NPPD behaves a dominated nucleation and a combination of co-crystallization with adsorption mechanism. This study provides a fundamental and microscopic perspective for the understanding of wax crystallization modification mechanism. |
| 语种 | 英语 |
| WOS记录号 | WOS:000429421200027 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/45901]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Wei; Gong, Jing |
| 作者单位 | 1.China Univ Petr, Beijing Key Lab Urban Oil & Gas Distribut Technol, Beijing 102249, Peoples R China 2.China Univ Petr, MOE Key Lab Petr Engn, Beijing 102249, Peoples R China 3.China Univ Petr, Natl Engn Lab Pipeline Safety, Beijing 102249, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Inst Chem, Zhongguancun North First St 2, Beijing 100190, Peoples R China 5.China Natl Offshore Oil Cooperat Res Ctr, Beijing 100027, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Huirong,Wang, Wei,Peng, Zeheng,et al. The influence of nanocomposite pour point depressant on the crystallization of waxy oil[J]. FUEL,2018,221:257-268. |
| APA | Huang, Huirong.,Wang, Wei.,Peng, Zeheng.,Ding, Yanfen.,Li, Kai.,...&Gong, Jing.(2018).The influence of nanocomposite pour point depressant on the crystallization of waxy oil.FUEL,221,257-268. |
| MLA | Huang, Huirong,et al."The influence of nanocomposite pour point depressant on the crystallization of waxy oil".FUEL 221(2018):257-268. |
入库方式： OAI收割
来源：化学研究所
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