中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A polymer design strategy toward green solvent processed efficient non-fullerene polymer solar cells

文献类型:期刊论文

作者Qin, Yunpeng1,2; Ye, Long3; Zhang, Shaoqing1,2; Zhu, Jie2; Yang, Bei2; Ade, Harald3; Hou, Jianhui1,2
刊名JOURNAL OF MATERIALS CHEMISTRY A
出版日期2018-03-14
卷号6期号:10页码:4324-4330
ISSN号2050-7488
DOI10.1039/c8ta00368h
英文摘要So far, the most successful and widely used solvents in polymer solar cells (PSCs) are chlorinated solvents like chloroform (CF), 1,2-dichlorobenzene (DCB) and chlorobenzene (CB), which are highly detrimental to human health and the environment. In this work, by the approach of manipulating flexible and conjugated side groups of a widely used polymer donor material (PBDB-T), two new polymers named PBDB-T-BO and PBDB-BzT are designed and synthesized to improve the solubility and fine-tune the aggregation property in tetrahydrofuran (THF), a much more benign solvent. As a result, an outstanding PCE of 12.10% was achieved with the THF-processed PBDB-BzT: IT-M device. The result in this work demonstrates the importance to modulate the aggregation effect of the polymer in solution by inserting conjugated groups and also suggests a feasible method to convert the main processing solvent of a highly efficient non-fullerene (NF)-PSC from CB into THF.
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000428847300010
源URL[http://ir.iccas.ac.cn/handle/121111/45967]  
专题中国科学院化学研究所
通讯作者Zhang, Shaoqing; Ade, Harald; Hou, Jianhui
作者单位1.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
3.North Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA
推荐引用方式
GB/T 7714
Qin, Yunpeng,Ye, Long,Zhang, Shaoqing,et al. A polymer design strategy toward green solvent processed efficient non-fullerene polymer solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(10):4324-4330.
APA Qin, Yunpeng.,Ye, Long.,Zhang, Shaoqing.,Zhu, Jie.,Yang, Bei.,...&Hou, Jianhui.(2018).A polymer design strategy toward green solvent processed efficient non-fullerene polymer solar cells.JOURNAL OF MATERIALS CHEMISTRY A,6(10),4324-4330.
MLA Qin, Yunpeng,et al."A polymer design strategy toward green solvent processed efficient non-fullerene polymer solar cells".JOURNAL OF MATERIALS CHEMISTRY A 6.10(2018):4324-4330.

入库方式: OAI收割

来源:化学研究所

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