中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Transform of Work Function of Poor-solvent Induced Active Layer Surface in All-polymer Solar Cells

文献类型:期刊论文

作者Li Hongai1; Song Chunpeng1; Qu Yi1,3; Zhang Jidong2
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
出版日期2018-02-10
卷号39期号:2页码:263-269
关键词All-polymer Solar Cell Solvent Annealing Work Function Of Active Layer Surface Diffuse
ISSN号0251-0790
DOI10.7503/cjcu20170502
英文摘要The binary of blend poly {4,8-bis [5-(2-ethylhexyl) thiophen-2-yl] benzo [1,2-b : 4,5-b'] dithiophe-ne-alt-3-flu-orothieno [3,4-b] thiophene-2-carboxy-late}(PTB7-Th) : poly{[N, N-bis(2-octyldode-cyl)-napthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}(N2200)(PTB7-Th : N2200) active layer films were annealed by methanol solvent-The difference of contact potential between active layer and gold-coated tip were increased from 37 mV to 160 mV, which means the surface work function decreased from 4.71 eV to 4.59 eV-XPS result showed that more N2200 diffused to surface of active layer during vapor annealing because there was a stronger interaction between poor polar solvent methanol and N2200-Such diffusion lead to the decrease of work function which was beneficial to promote energy match between electrode and active layer and the formation of better ohmic contact, which resulted in the over 10% enhance of power conversion efficiency of corresponding organic solar cells.
语种英语
WOS记录号WOS:000429847300011
出版者HIGHER EDUCATION PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/46033]  
专题中国科学院化学研究所
通讯作者Qu Yi; Zhang Jidong
作者单位1.Changchun Univ Sci & Technol, State Key Lab High Power Semicond Lasers, Changchun 130022, Jilin, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China
3.Hainan Normal Univ, Coll Phys & Elect Engn, Haikou 571158, Hainan, Peoples R China
推荐引用方式
GB/T 7714
Li Hongai,Song Chunpeng,Qu Yi,et al. Transform of Work Function of Poor-solvent Induced Active Layer Surface in All-polymer Solar Cells[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2018,39(2):263-269.
APA Li Hongai,Song Chunpeng,Qu Yi,&Zhang Jidong.(2018).Transform of Work Function of Poor-solvent Induced Active Layer Surface in All-polymer Solar Cells.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,39(2),263-269.
MLA Li Hongai,et al."Transform of Work Function of Poor-solvent Induced Active Layer Surface in All-polymer Solar Cells".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 39.2(2018):263-269.

入库方式: OAI收割

来源:化学研究所

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