Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor
文献类型：期刊论文
| 作者 | Zhang, Shuai1; Shi, Xiaoze1; Moszynski, Dariusz1; Tang, Tao2; Chu, Paul K.3,4; Chen, Xuecheng1,2; Mijowska, Ewa1 |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2018-04-10 |
| 卷号 | 269页码:580-589 |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2018.03.043 |
| 英文摘要 | The accessible surface area, conductivity, and pore size determine the capacitive properties of carbon-based materials. In this work, hierarchical nanoporous carbon (NPC) materials with a large specific surface area, high conductivity, and suitable pore size are prepared from nanoscaled Al-based metal-organic complex (Al-MOC) by annealing. The annealing temperature has a profound influence on the morphology of the NPC materials which in turn impact the electrochemical performance. Compared to annealing at a low temperature, an interconnected structure is formed at an annealing temperature exceeding 950 degrees C to produce a larger accessible surface area. Owing to the interconnected structure and high conductivity, sample NPC-950 with the two-electrode configuration has the highest specific capacitance and the best stability. The specific capacitances are 298 Fg(-1) at a scanning rate of 1 mVs(-1) in symmetrical supercapacitor device. These values are the largest values reported from ultrapure carbon-based EDLCs in an aqueous electrolyte so far. Furthermore, 96.73% of the capacity is retained after 5000 cycles in 1 MH2SO4 electrolyte. In an organic electrolyte, the supercapacitor cells composed of NPC produce an energy density of 43 Wh kg(-1). The NPC materials with large specific capacity and excellent stability produced by the simple and cost effective technique have large potential in supercapacitors. (c) 2018 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000428806700066 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46035]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Tao; Chu, Paul K.; Chen, Xuecheng |
| 作者单位 | 1.West Pomeranian Univ Technol Szczecin, Nanomat Physicochem Dept, Al Piastow 45, PL-70311 Szczecin, Poland 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Renmin St 5625, Changchun 130022, Peoples R China 3.City Univ Hong Kong, Dept Phys, Tat Chee Ave, Kowloon, Hong Kong, Peoples R China 4.City Univ Hong Kong, Dept Mat Sci & Engn, Tat Chee Ave, Kowloon, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Shuai,Shi, Xiaoze,Moszynski, Dariusz,et al. Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor[J]. ELECTROCHIMICA ACTA,2018,269:580-589. |
| APA | Zhang, Shuai.,Shi, Xiaoze.,Moszynski, Dariusz.,Tang, Tao.,Chu, Paul K..,...&Mijowska, Ewa.(2018).Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor.ELECTROCHIMICA ACTA,269,580-589. |
| MLA | Zhang, Shuai,et al."Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor".ELECTROCHIMICA ACTA 269(2018):580-589. |
入库方式： OAI收割
来源：化学研究所
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