Polymorph selection during crystallization of random copolymers
文献类型:期刊论文
作者 | Lai, Yuqing; Men, Yongfeng |
刊名 | EUROPEAN POLYMER JOURNAL
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出版日期 | 2018-04-01 |
卷号 | 101页码:218-224 |
关键词 | Random Copolymer Polymorphs Crystallization Butene-1/ethylene Copolymer |
ISSN号 | 0014-3057 |
DOI | 10.1016/j.eurpolymj.2018.02.038 |
英文摘要 | Many polymers show polymorphous behavior that they can crystallize into different crystalline modifications under different circumstances. For a particular polymer material, in most of the cases, one of the several possible modifications is generally preferentially developed. Therefore, selective control of the specific polymorphous modification thus properties in polymeric materials is highly desired. This article discusses underlying mechanism of polymorph selection during crystallization of random copolymers. Following a general discussion of theoretical considerations, we present case studies of butene-l/ethylene and propylene/ethylene random copolymers. Our results indicate that polymorph selection during crystallization of random copolymers is primarily controlled by the nucleation process. Nucleation of different polymorphs can be easily tuned via creating differently structured melt. |
语种 | 英语 |
WOS记录号 | WOS:000430628800026 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/46043] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Men, Yongfeng |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Renmin St 5625, Changchun 130022, Jilin, Peoples R China |
推荐引用方式 GB/T 7714 | Lai, Yuqing,Men, Yongfeng. Polymorph selection during crystallization of random copolymers[J]. EUROPEAN POLYMER JOURNAL,2018,101:218-224. |
APA | Lai, Yuqing,&Men, Yongfeng.(2018).Polymorph selection during crystallization of random copolymers.EUROPEAN POLYMER JOURNAL,101,218-224. |
MLA | Lai, Yuqing,et al."Polymorph selection during crystallization of random copolymers".EUROPEAN POLYMER JOURNAL 101(2018):218-224. |
入库方式: OAI收割
来源:化学研究所
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