Spectroscopic identification towards tunable mesoscale aggregates of zinc tetraphenylporphyrin for materials
文献类型:期刊论文
作者 | An, Pan1; Kang, Longtian2; Tang, Zhen3; Su, Peifeng3; Luo, Zhixun1 |
刊名 | CHINESE CHEMICAL LETTERS
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出版日期 | 2018-03-01 |
卷号 | 29期号:3页码:361-365 |
关键词 | Zntpp Molecular Aggregates Intermolecular Interactions Ramanspectroscopy Xrd |
ISSN号 | 1001-8417 |
DOI | 10.1016/j.cclet.2017.11.009 |
英文摘要 | We present a study of spectroscopic identification towards the molecular aggregates of zinc tetraphenylporphyrin (ZnTPP) illustrating how the energy states and intermolecular interactions determine the tunable properties of functional materials in condensation processes. Distinguishable fingerprints of ZnTPP nanorods and nanosheets are addressed utilizing X-ray diffraction (XRD), Raman and UV-vis absorption spectroscopies. Although these ZnTPPs are assigned to j-aggregation at different extent, the spectral analysis reveals a significant role of the intermolecular interactions associated with varying mesoscale architectures. Energy decomposition analysis (EDA) revealed that the varied ZnTPP aggregates are stabilized by altered dispersion interactions due to the dominant pi center dot center dot center dot pi stacking between the monomers. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000429392800005 |
出版者 | ELSEVIER SCIENCE INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/46069] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Su, Peifeng; Luo, Zhixun |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Fujian Inst Res Struct Matter Fujian, Fuzhou 350002, Fujian, Peoples R China 3.Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China |
推荐引用方式 GB/T 7714 | An, Pan,Kang, Longtian,Tang, Zhen,et al. Spectroscopic identification towards tunable mesoscale aggregates of zinc tetraphenylporphyrin for materials[J]. CHINESE CHEMICAL LETTERS,2018,29(3):361-365. |
APA | An, Pan,Kang, Longtian,Tang, Zhen,Su, Peifeng,&Luo, Zhixun.(2018).Spectroscopic identification towards tunable mesoscale aggregates of zinc tetraphenylporphyrin for materials.CHINESE CHEMICAL LETTERS,29(3),361-365. |
MLA | An, Pan,et al."Spectroscopic identification towards tunable mesoscale aggregates of zinc tetraphenylporphyrin for materials".CHINESE CHEMICAL LETTERS 29.3(2018):361-365. |
入库方式: OAI收割
来源:化学研究所
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