Inert C-H Bond Transformations Enabled by Organometallic Manganese Catalysis
文献类型：期刊论文
| 作者 | Hu, Yuanyuan; Zhou, Bingwei; Wang, Congyang |
| 刊名 | ACCOUNTS OF CHEMICAL RESEARCH
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 51期号:3页码:816-827 |
| ISSN号 | 0001-4842 |
| DOI | 10.1021/acs.accounts.8b00028 |
| 英文摘要 | Traditional organic synthesis relies heavily on the transformations of various preinstalled functional groups, such as cross-coupling reactions using organohalides and organometallic reagents. The strategy of C-H activation enables the direct formation of C-C/C-X (X = heteroatom) bonds from inert C-H bonds, which can enhance the atom- and step-economy of organic synthesis. To date, precious metals have overwhelmingly dominated the C-H activation field; however, the rarity and high cost of these metals necessitate the development of more sustainable catalysts. In this regard, catalysts based on manganese are highly desirable owing to the abundant reserve of manganese in the earths crust and its economic benefits, low toxicity, and potentially unique reactivity. Although the first stoichiometric manganese-mediated C-H activation reaction was reported as early as 1970, manganese-catalyzed C-H activation reactions are largely underdeveloped. How to construct an efficient catalytic cycle for manganese in C-H activation reactions remains as a key issue to be addressed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000428219800028 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46091]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Congyang |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Yuanyuan,Zhou, Bingwei,Wang, Congyang. Inert C-H Bond Transformations Enabled by Organometallic Manganese Catalysis[J]. ACCOUNTS OF CHEMICAL RESEARCH,2018,51(3):816-827. |
| APA | Hu, Yuanyuan,Zhou, Bingwei,&Wang, Congyang.(2018).Inert C-H Bond Transformations Enabled by Organometallic Manganese Catalysis.ACCOUNTS OF CHEMICAL RESEARCH,51(3),816-827. |
| MLA | Hu, Yuanyuan,et al."Inert C-H Bond Transformations Enabled by Organometallic Manganese Catalysis".ACCOUNTS OF CHEMICAL RESEARCH 51.3(2018):816-827. |
入库方式： OAI收割
来源：化学研究所
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