Aromatic Aminocatalysis
文献类型：期刊论文
| 作者 | Lv, Jian1,2; Zhang, Qi1,2; Cai, Mao1,2; Han, Yanfang1,2; Luo, Sanzhong1,2 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2018-04-04 |
| 卷号 | 13期号:7页码:740-753 |
| 关键词 | Aminocatalysis Asymmetric Catalysis Bioconjugation C-h Activation Organocatalysis |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201701773 |
| 英文摘要 | Aromatic aminocatalysis refers to transformations that employ aromatic amines, such as anilines or aminopyridines, as catalysts. Owing to the conjugation of the amine moiety with the aromatic ring, aromatic amines demonstrate distinctive features in aminocatalysis compared with their aliphatic counterparts. For example, aromatic aminocatalysis typically proceeds with slower turnover, but is more active and conformationally rigid as a result of the stabilized aromatic imine or iminium species. In fact, the advent of aromatic aminocatalysis can be traced back to before the renaissance of organocatalysis in the early 2000s. So far, aromatic aminocatalysis has been widely applied in bioconjugation reactions through transamination; in asymmetric organocatalysis through imine/enamine tautomerization; and in cooperative catalysis with transition metals through C-H/C-C activation and functionalization. This Focus Review summarizes the advent of and major advances in the use of aromatic aminocatalysis in bioconjugation reactions and organic synthesis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000429415400003 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46111]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Luo, Sanzhong |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Jian,Zhang, Qi,Cai, Mao,et al. Aromatic Aminocatalysis[J]. CHEMISTRY-AN ASIAN JOURNAL,2018,13(7):740-753. |
| APA | Lv, Jian,Zhang, Qi,Cai, Mao,Han, Yanfang,&Luo, Sanzhong.(2018).Aromatic Aminocatalysis.CHEMISTRY-AN ASIAN JOURNAL,13(7),740-753. |
| MLA | Lv, Jian,et al."Aromatic Aminocatalysis".CHEMISTRY-AN ASIAN JOURNAL 13.7(2018):740-753. |
入库方式： OAI收割
来源：化学研究所
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