Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage
文献类型：期刊论文
| 作者 | Wang, Ning1; Li, Xiaodong1,2; Tu, Zeyi2,3; Zhao, Fuhua1; He, Jianjiang1; Guan, Zhaoyong1; Huang, Changshui1; Yi, Yuanping3; Li, Yuliang3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-04-03 |
| 卷号 | 57期号:15页码:3968-3973 |
| 关键词 | Boron Carbon Materials Electrochemistry Energy Storage Graphdiyne |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201800453 |
| 英文摘要 | Boron-graphdiyne (BGDY), which has a unique pi-conjugated structure comprising an sp-hybridized carbon skeleton and evenlydistributed boron heteroatoms in a well-organized 2D molecular plane, is prepared through a bottom-up synthetic strategy. Excellent conductivity, a relatively low band gap and a packing mode of the planar BGDY are observed. Notably, the unusual bonding environment of the all sp-carbon framework and the electron-deficient boron centers generates affinity to metal atoms, and thus provides extra binding sites. Furthermore, the expanded molecule pores of the BGDY molecular plane can also facilitate the transfer of metal ions in the perpendicular direction. The practical effect of the all sp-carbon structure and boron heteroatoms on the properties of BGDY are demonstrated in its performance as the anode in sodium-ion batteries. |
| 语种 | 英语 |
| WOS记录号 | WOS:000428350200017 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46123]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Changshui; Li, Yuliang |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Organ Solids, BNLMS, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ning,Li, Xiaodong,Tu, Zeyi,et al. Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(15):3968-3973. |
| APA | Wang, Ning.,Li, Xiaodong.,Tu, Zeyi.,Zhao, Fuhua.,He, Jianjiang.,...&Li, Yuliang.(2018).Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(15),3968-3973. |
| MLA | Wang, Ning,et al."Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.15(2018):3968-3973. |
入库方式： OAI收割
来源：化学研究所
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