Asymmetric Fluorination of alpha-Branched Aldehydes by Chiral Primary Amine Catalysis: Reagent-Controlled Enantioselectivity Switch
文献类型：期刊论文
| 作者 | Cui, Linfeng1; You, Yang'en2; Mi, Xueling1; Luo, Sanzhong2 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2018-04-06 |
| 卷号 | 83期号:7页码:4250-4256 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.8b00279 |
| 英文摘要 | Asymmetric fluorination of alpha-branched aldehydes catalyzed by chiral primary amines under mild conditions has been developed. Both enantiomers could be obtained with good yields (up to 96%) and a high enantioselectivity (up to 90% ee) by a simple swap of the fluorination reagents. |
| 语种 | 英语 |
| WOS记录号 | WOS:000429886100086 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46161]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Mi, Xueling; Luo, Sanzhong |
| 作者单位 | 1.Beijing Normal Univ, Coll Chem, Xinjiekouwai St 19, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Linfeng,You, Yang'en,Mi, Xueling,et al. Asymmetric Fluorination of alpha-Branched Aldehydes by Chiral Primary Amine Catalysis: Reagent-Controlled Enantioselectivity Switch[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(7):4250-4256. |
| APA | Cui, Linfeng,You, Yang'en,Mi, Xueling,&Luo, Sanzhong.(2018).Asymmetric Fluorination of alpha-Branched Aldehydes by Chiral Primary Amine Catalysis: Reagent-Controlled Enantioselectivity Switch.JOURNAL OF ORGANIC CHEMISTRY,83(7),4250-4256. |
| MLA | Cui, Linfeng,et al."Asymmetric Fluorination of alpha-Branched Aldehydes by Chiral Primary Amine Catalysis: Reagent-Controlled Enantioselectivity Switch".JOURNAL OF ORGANIC CHEMISTRY 83.7(2018):4250-4256. |
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来源：化学研究所
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