Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis
文献类型：期刊论文
| 作者 | Lang, Xianjun1; Zhao, Jincai2 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2018-03-16 |
| 卷号 | 13期号:6页码:599-613 |
| 关键词 | Oxidation Photocatalysis Radicals Synthesis Design Visible Light |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201701765 |
| 英文摘要 | Visible light has risen to become a very important facilitator for selective radical reactions enabled by well-cognized photocatalysts. The renaissance of visible-light photocatalysis on this matter partly relies on integrating it with other fields of catalysis. In parallel, 2,2,6,6-tetramethylpiperidin N-oxide (TEMPO), a quintessential persistent radical, has a wide range of uses owing to its exceptional redox behavior, which gives rise to its latest prominence in catalysis. Therefore, integrating the catalysis of TEMPO with photocatalysis to perform visible-light-induced selective reactions becomes a very convenient marriage of merits. In this context, the integration of different types of photocatalysts, including metal complexes, metal-free organic dyes, and semiconductors, with TEMPO for outstanding organic transformations will be summarized. To expand further the catalytic repertoire, the integration of TEMPOH analogues such as NHPI (N-hydroxyphthalimide) and NHS (N-hydroxysuccinimide) with photocatalysis will also be discussed. Hopefully, these advances will pave the way for more breakthroughs by integrating TEMPO and its analogues with photocatalysis to lead to a valuable blueprint for visible-light-induced selective organic transformations. |
| 语种 | 英语 |
| WOS记录号 | WOS:000428378000002 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46251]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Lang, Xianjun |
| 作者单位 | 1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lang, Xianjun,Zhao, Jincai. Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis[J]. CHEMISTRY-AN ASIAN JOURNAL,2018,13(6):599-613. |
| APA | Lang, Xianjun,&Zhao, Jincai.(2018).Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis.CHEMISTRY-AN ASIAN JOURNAL,13(6),599-613. |
| MLA | Lang, Xianjun,et al."Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis".CHEMISTRY-AN ASIAN JOURNAL 13.6(2018):599-613. |
入库方式： OAI收割
来源：化学研究所
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