Novel hydroxyl-substituted perylene-3,4,9,10-tetracarboxylic acid diimides for selective recognition of fluoride
文献类型：期刊论文
| 作者 | Wang, Ran1; Ma, Yongshan2; Zhao, Jianfeng3,4; Zhang, Andong5; Yang, Shufan1; Shen, Han1; Li, Gang1; Shi, Zhiqiang1 |
| 刊名 | SENSORS AND ACTUATORS B-CHEMICAL
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 260页码:719-726 |
| 关键词 | Perylene Diimides Sensor Fluoride Detection Intermolecular Proton Transfer Fluorescence |
| ISSN号 | 0925-4005 |
| DOI | 10.1016/j.snb.2017.12.171 |
| 英文摘要 | Two novel highly fluorescent hydroxyl-substituted perylene diimides derivatives, N,N-dicyclohexyl-1-hydroxyperylenediimide (1) 2,9-dicyclohexy1-5,5-dimethyl-12-hydroxy-5,6-dihydropyreno [2,1,10-def:7,8,9-d'e'f']diisoquinoline-6-oxa-1,3,8,10(2H,9H)-tetraone (2) were designed and efficiently synthesized through a single aromatic nucleophilic displacement reaction. The physical properties of the as-prepared compounds had been fully studied. Both receptors have shown no affinity for other anions, such as Cl-, Br-, I-, SO4-, PF6-, H2PO4, BF4-, AcO-, ClO4- (as salt of tetra-n-butylammonia) and ammonium hydroxide. Interestingly, they can be served as colorimetric and fluorescent chemodosimeter for fluoride ion using hydroxyl as binding sites, which was the first report of hydroxyl-modified PDIs based photodetector of fluoride ion. Upon addition of F- anion to compound 2 solution, dramatic color change and fluorescence quenching were observed. Furthermore, the red-shifted maximum absorption wavelength reached 207 nm to the far-red region, which was the maximal spectrum bathochromic-shift of PDIs used in fluoride detection. In addition, the two fluoride sensor can be used under illumination from a laboratory hand-held UV lamp. These results demonstrated that using facile synthetic routes to constructing PDIs molecules with hydroxyl moiety was a useful strategy for designing high performance fluoride recognization. (C) 2018 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000424884300085 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46259]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Gang; Shi, Zhiqiang |
| 作者单位 | 1.Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Shandong Prov Key Lab Clean Prod Fine Chem,Key La, Minist Educ,Inst Mat & Clean Energy,Coll Chem Che, Jinan 250014, Shandong, Peoples R China 2.Shandong Jianzhu Univ, Sch Municipal & Environm Engn, Jinan 250014, Shandong, Peoples R China 3.Nanjing Tech Univ Nanjing Tech, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, KLOFE, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China 4.Nanjing Tech Univ Nanjing Tech, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, IAM, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ran,Ma, Yongshan,Zhao, Jianfeng,et al. Novel hydroxyl-substituted perylene-3,4,9,10-tetracarboxylic acid diimides for selective recognition of fluoride[J]. SENSORS AND ACTUATORS B-CHEMICAL,2018,260:719-726. |
| APA | Wang, Ran.,Ma, Yongshan.,Zhao, Jianfeng.,Zhang, Andong.,Yang, Shufan.,...&Shi, Zhiqiang.(2018).Novel hydroxyl-substituted perylene-3,4,9,10-tetracarboxylic acid diimides for selective recognition of fluoride.SENSORS AND ACTUATORS B-CHEMICAL,260,719-726. |
| MLA | Wang, Ran,et al."Novel hydroxyl-substituted perylene-3,4,9,10-tetracarboxylic acid diimides for selective recognition of fluoride".SENSORS AND ACTUATORS B-CHEMICAL 260(2018):719-726. |
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来源：化学研究所
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