Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution
文献类型：期刊论文
| 作者 | Xiong, Zhichao1; Pei, Chengfeng1; Xue, Peng1; Lv, Hui1,2,3; Zhang, Xumu4 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2018-04-17 |
| 卷号 | 54期号:31页码:3883-3886 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c8cc01643g |
| 英文摘要 | Highly enantioselective transfer hydrogenation of -keto sulfonamides was developed via dynamic kinetic resolution using a chiral Ru(ii) catalyst with an azeotropic solution of HCO2H/Et3N as a hydrogen donor, affording -substituted -hydroxyl sulfonamides in good yields with excellent diastereo- and enantioselectivities. This method is featured with mild conditions, easy operation, and a broad substrate scope, which make it possible to find wide applications in the synthesis of natural products and biologically active compounds containing the -substituted -hydroxyl sulfonamide core. |
| 语种 | 英语 |
| WOS记录号 | WOS:000430022100020 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46263]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Lv, Hui; Zhang, Xumu |
| 作者单位 | 1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Wuhan Univ, Coll Chem & Mol Sci, Minist Educ, Engn Res Ctr Organosilicon Cpds & Mat, Wuhan 430072, Hubei, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 4.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Zhichao,Pei, Chengfeng,Xue, Peng,et al. Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution[J]. CHEMICAL COMMUNICATIONS,2018,54(31):3883-3886. |
| APA | Xiong, Zhichao,Pei, Chengfeng,Xue, Peng,Lv, Hui,&Zhang, Xumu.(2018).Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution.CHEMICAL COMMUNICATIONS,54(31),3883-3886. |
| MLA | Xiong, Zhichao,et al."Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution".CHEMICAL COMMUNICATIONS 54.31(2018):3883-3886. |
入库方式： OAI收割
来源：化学研究所
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