A quasi-ordered bulk heterojunction of P3HT/PCBM solar cells fabricated by zone-casting
文献类型：期刊论文
| 作者 | Liu, Jiangang; Gao, Xiang; Sun, Yue; Han, Yanchun |
| 刊名 | SOLAR ENERGY MATERIALS AND SOLAR CELLS
 |
| 出版日期 | 2013-10-01 |
| 卷号 | 117页码:421-428 |
| 关键词 | Photovoltaic Cells Polythiophene Zone-casting Grain Boundary |
| ISSN号 | 0927-0248 |
| DOI | 10.1016/j.solmat.2013.06.031 |
| 英文摘要 | In this paper, a quasi-ordered bulk hetertojunction of P3HT/PCBM solar cells (Q-O BHJ device) was fabricated by zone-casting from the solutions with different aging times. P3HT nanofibers aligned in an oriented manner due to the shear stress and solute concentration gradient during zone-casting process. The orientation degree of P3HT nanofibers increased when the aging time of solution was prolonged. Meanwhile, P3HT had a high crystallinity due to the slow evaporation rate of solvent during the filmforming process. The oriented alignment of nanofibers could facilitate the connection between nanofibers by increasing the bridging chains. Furthermore, the bridging chains tended to adopt an untwisted conformation, which results in a reduced energy barrier of hole transfer. As a consequence, the Q-O BHJ device had a higher fill factor (FF) and short-circuit current density (I) compared with the device fabricated by spin coating (BHJ device), leading to an increase by almost more than 50% in device efficiency and a PCE of 3.26% without any annealing treatment. Published by Elsevier B.V. |
| 语种 | 英语 |
| WOS记录号 | WOS:000325188400065 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46293]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Yanchun |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jiangang,Gao, Xiang,Sun, Yue,et al. A quasi-ordered bulk heterojunction of P3HT/PCBM solar cells fabricated by zone-casting[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2013,117:421-428. |
| APA | Liu, Jiangang,Gao, Xiang,Sun, Yue,&Han, Yanchun.(2013).A quasi-ordered bulk heterojunction of P3HT/PCBM solar cells fabricated by zone-casting.SOLAR ENERGY MATERIALS AND SOLAR CELLS,117,421-428. |
| MLA | Liu, Jiangang,et al."A quasi-ordered bulk heterojunction of P3HT/PCBM solar cells fabricated by zone-casting".SOLAR ENERGY MATERIALS AND SOLAR CELLS 117(2013):421-428. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。