Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator
文献类型：期刊论文
| 作者 | Fu, Hongwei1,2; Li, Jing1,2; Zhang, Zilong1; Zhan, Hongmei1; Li, Xiao1; Cheng, Yanxiang1 |
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2013-08-15 |
| 卷号 | 738页码:55-58 |
| 关键词 | Palladium Complex Catalyst Chain-growth Polycondensation Conjugated Polymer |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2013.04.016 |
| 英文摘要 | Dinuclear Pd(II) complex DiPd-DPE with a bridging ligand C6H4OC6H4-4,4' was successfully synthesized by double oxidative addition reaction of Pd(PCy3)(4) with 4,4'-dibromodiphenyl ether in good yield. X-ray crystal structure analysis reveals that the Pd atoms have the nearly square-planar coordination geometry with the similar bond lengths of two Pd-Br as well as four Pd-P, implying that two Pd(II) centers have similar reactivity. Using the dinuclear Pd(II) complex DiPd-DPE as an initiator, novel polyfluorene (PF) with a defined group (C6H4OC6H4-4,4') in the middle of polymer main chain was prepared, demonstrated by MALDI-TOF analysis. (C) 2013 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000319458900009 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46297]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, Hongmei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Hongwei,Li, Jing,Zhang, Zilong,et al. Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2013,738:55-58. |
| APA | Fu, Hongwei,Li, Jing,Zhang, Zilong,Zhan, Hongmei,Li, Xiao,&Cheng, Yanxiang.(2013).Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator.JOURNAL OF ORGANOMETALLIC CHEMISTRY,738,55-58. |
| MLA | Fu, Hongwei,et al."Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator".JOURNAL OF ORGANOMETALLIC CHEMISTRY 738(2013):55-58. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。