中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Vapor-assisted imprinting to pattern poly(3-hexylthiophene) (P3HT) film with oriented arrangement of nanofibrils and flat-on conformation of P3HT chains

文献类型:期刊论文

作者Liu, Jiangang; Sun, Yue; Zheng, Lidong; Geng, Yanhou; Han, Yanchun
刊名POLYMER
出版日期2013-01-08
卷号54期号:1页码:423-430
关键词Polythiophene Crystallographic Transition Hierarchical Ordered Structure
ISSN号0032-3861
DOI10.1016/j.polymer.2012.11.011
英文摘要Poly(3-hexylthiophene) (P3HT) film with a hierarchical ordered structure was fabricated by an approach combining vapor-assisted imprinting in a carbon disulfide (CS2) atmosphere and thermal annealing treatment. In the hierarchical ordered structure, P3HT domains are vertically arranged and the domains are constituted by uniaxially aligned P3HT nanofibrils, furthermore, the chains in it adopted flat-on conformation. The vertically arranged domains are formed by the action of capillarity, the oriented nanofibrils are induced by the crystallization nucleation of P3HT and the directional evaporation of the solvent, and the flat-on conformation of P3HT chains are induced by the enhanced intermolecular interaction of the alkyl side chains in CS2 atmosphere. The arrangement behavior of P3HT crystals and chains facilitate the bridging chains link neighboring grains with minimal distortion, while the enhanced intermolecular interaction enable the formation of larger P3HT crystals, and then reduce the quantity of grain boundary. As a result, this ordered structure provides more delocalized electrons along the direction that perpendicular to the substrate, which would result in an improvement of the carrier mobility along this direction. (C) 2012 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000322356000048
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/46309]  
专题中国科学院化学研究所
通讯作者Han, Yanchun
作者单位Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Liu, Jiangang,Sun, Yue,Zheng, Lidong,et al. Vapor-assisted imprinting to pattern poly(3-hexylthiophene) (P3HT) film with oriented arrangement of nanofibrils and flat-on conformation of P3HT chains[J]. POLYMER,2013,54(1):423-430.
APA Liu, Jiangang,Sun, Yue,Zheng, Lidong,Geng, Yanhou,&Han, Yanchun.(2013).Vapor-assisted imprinting to pattern poly(3-hexylthiophene) (P3HT) film with oriented arrangement of nanofibrils and flat-on conformation of P3HT chains.POLYMER,54(1),423-430.
MLA Liu, Jiangang,et al."Vapor-assisted imprinting to pattern poly(3-hexylthiophene) (P3HT) film with oriented arrangement of nanofibrils and flat-on conformation of P3HT chains".POLYMER 54.1(2013):423-430.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。