Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization
文献类型：期刊论文
| 作者 | Liu, Feng1,2; Tan, Hai-ying1,2; Tang, Tao1 |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2013-12-01 |
| 卷号 | 31期号:12页码:1647-1659 |
| 关键词 | Anionic Polymerization Butadiene P-methylstyrene Random Copolymer Gradient Copolymer |
| ISSN号 | 0256-7679 |
| DOI | 10.1007/s10118-013-1357-x |
| 英文摘要 | Copolymers of 1,3-butadiene and p-methylstyrene (p-MS) were synthesized via anionic polymerization. A benzophenone-potassium complex was added to tune the reactivity ratio of the two monomers, leading to random and gradient composition along the copolymer chain. The overall composition and microstructure could be controlled and well characterized by GPC and H-1-NMR. The p-MS was distributed from gradient to random with increasing the content of the benzophenone-potassium complex, and the 1,2-microstructure in the polybutadiene sequence increased at the same time. The hydrogenation of the copolymer of 1,3-butadiene and p-MS resulted in the corresponding saturated copolymer with welldefined structure and narrow molecular weight distribution. |
| 语种 | 英语 |
| WOS记录号 | WOS:000326884900005 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46319]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Feng,Tan, Hai-ying,Tang, Tao. Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2013,31(12):1647-1659. |
| APA | Liu, Feng,Tan, Hai-ying,&Tang, Tao.(2013).Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization.CHINESE JOURNAL OF POLYMER SCIENCE,31(12),1647-1659. |
| MLA | Liu, Feng,et al."Synthesis and characterization of random or gradient butadiene-p-methylstyrene copolymers via anionic polymerization".CHINESE JOURNAL OF POLYMER SCIENCE 31.12(2013):1647-1659. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。