In situ self-polymerization of unsaturated metal methacrylate and its dispersion mechanism in rubber-based composites
文献类型：期刊论文
| 作者 | Wen, Shipeng1; Zhou, Yao1; Yao, Lu1; Zhang, Liqun2; Chan, Tung W.3; Liang, Yongri4; Liu, Li1 |
| 刊名 | THERMOCHIMICA ACTA
 |
| 出版日期 | 2013-11-10 |
| 卷号 | 571页码:15-20 |
| 关键词 | In Situ Self-polymerization Unsaturated Metal Methacrylate Rubber Composite Differential Scanning Calorimetry |
| ISSN号 | 0040-6031 |
| DOI | 10.1016/j.tca.2013.08.022 |
| 英文摘要 | Unsaturated metal methacrylate (UMM) as one kind of functional filler has played an important role in reinforcing rubber materials. The in situ self-polymerization of UMM in UMM/rubber composite leads to the uniform dispersion of poly(UMM) in the rubber matrix, while the crosslinking of rubber and grafting between UMM and rubber chains occur simultaneously, making it difficult to clarify the effect of the in situ polymerization on the dispersion of poly(UMM) in the rubber matrix. In this work, we investigated the dispersion mechanism of UMM without rubber matrix for the first time using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. Three types of UMMs including zinc methacrylate (Zn(MA)(2)), sodium methacrylate (Na(MA)) and samarium methacrylate (Sm(MA)(3)) were chosen to investigate the in situ self-polymerization of UMM. Based on DSC results, we conclude that the crystals with low melting point tend to self-polymerize first and generate a large amount of heat in the presence of peroxide. The high heat of reaction can melt the crystals with high melting point, and more UMM molecules are dissolved in the rubber matrix, thus increasing the extent of the in situ polymerization. Hence, the UMM with low melting point can self-polymerize to a large extent. Our findings provide in-depth understanding of the dispersion mechanism of UMM in rubber. (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000328235100003 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46321]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Li |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China 3.Virginia Polytech Inst & State Univ, Dept Mat Sci & Engn, Blacksburg, VA 24061 USA 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, Shipeng,Zhou, Yao,Yao, Lu,et al. In situ self-polymerization of unsaturated metal methacrylate and its dispersion mechanism in rubber-based composites[J]. THERMOCHIMICA ACTA,2013,571:15-20. |
| APA | Wen, Shipeng.,Zhou, Yao.,Yao, Lu.,Zhang, Liqun.,Chan, Tung W..,...&Liu, Li.(2013).In situ self-polymerization of unsaturated metal methacrylate and its dispersion mechanism in rubber-based composites.THERMOCHIMICA ACTA,571,15-20. |
| MLA | Wen, Shipeng,et al."In situ self-polymerization of unsaturated metal methacrylate and its dispersion mechanism in rubber-based composites".THERMOCHIMICA ACTA 571(2013):15-20. |
入库方式： OAI收割
来源：化学研究所
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