Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid
文献类型：期刊论文
| 作者 | Li Yu-han1; Wang Wei-jian1; Jin Ri-zhe2; Gao Lian-xun2 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2013-12-01 |
| 卷号 | 29期号:6页码:1225-1228 |
| 关键词 | Sulfonated Polyimide Proton Conductivity Proton-exchange Membrane |
| ISSN号 | 1005-9040 |
| DOI | 10.1007/s40242-013-3076-9 |
| 英文摘要 | A novel sulfonated diamine monomer, 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid(BAPNS), was synthesized. A series of sulfonated polyimide copolymers was prepared from BAPNS, 1,4,5,8-naphthalenetetra-carboxylic dianhydride(NTDA) and nonsulfonated diamine 4,4'-diaminodiphenyl ether(ODA). Flexible, transparent, and mechanically strong membranes were obtained. The novel sulfonated polyimide(SPI) membranes show higher conductivity, for example, SPI-100 shows a conductivity of 0.0698 S/cm at 80 A degrees C(SPI-X: X refers to molar fraction of BAPNS). The membranes exhibit the permeability of methanol from 2.18x10(-7) cm(2)/s to 2.57x10(-7) cm(2)/s, which is much lower than that of Nafion(2.00x10(-6) cm(2)/s). The copolymers were thermally stable up to 330 A degrees C. The sulfonated polyimide copolymers also show reasonable mechanical strength; for example, the maximum tensile strength at break of the sulfonated polyimide copolymer with 100%(molar fraction) BAPNS is 1.35 GPa under high moisture conditions. The optimum concentration of BAPNS was found to be 100%(molar fraction) from the view point of proton conductivity, methanol permeability, and membrane stability. |
| 语种 | 英语 |
| WOS记录号 | WOS:000329095200040 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46337]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao Lian-xun |
| 作者单位 | 1.Jilin Business & Technol Coll, Coll Food Sci & Engn, Changchun 130062, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Yu-han,Wang Wei-jian,Jin Ri-zhe,et al. Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2013,29(6):1225-1228. |
| APA | Li Yu-han,Wang Wei-jian,Jin Ri-zhe,&Gao Lian-xun.(2013).Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,29(6),1225-1228. |
| MLA | Li Yu-han,et al."Synthesis and characterization of novel sulfonated polyimides from 4,6-bis(4-aminophenoxy)-naphthalene-2-sulfonic acid".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 29.6(2013):1225-1228. |
入库方式： OAI收割
来源：化学研究所
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