Third-order nonlinear optical properties of a series of porphyrin-appended europium(III) bis(phthalocyaninato) complexes
文献类型：期刊论文
| 作者 | Chen, Li1; Hu, Rui1; Xu, Jian1; Wang, Shuangqing1; Li, Xiyou2; Li, Shayu1; Yang, Guoqiang1 |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2013-03-15 |
| 卷号 | 105页码:577-581 |
| 关键词 | Porphyrin-appended Europium(Iii) Bis(Phthalocyaninato) Complexes Nonlinear Optical Property Z-scan Charge Transfer |
| ISSN号 | 1386-1425 |
| DOI | 10.1016/j.saa.2012.12.063 |
| 英文摘要 | The third-order nonlinear optical properties of a series of phthalocyanine-porphyrin complexes containing a sandwich-type bis(phthalocyaninato) europium(III) core and one or two zinc(II) porphyrin unit(s) were investigated by Z-scan techniques at 1064 nm. The second-order molecular hyperpolarizabilities of these complexes are in the order of 10(-30) esu. The enhanced nonlinear properties are induced by the high delocalization of the electrons in the sandwich molecular structure, which may result in charge transfer between the central metal and the phthalocyanine ligands. (C) 2012 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317545400078 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46369]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Shuangqing |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China 2.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Li,Hu, Rui,Xu, Jian,et al. Third-order nonlinear optical properties of a series of porphyrin-appended europium(III) bis(phthalocyaninato) complexes[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2013,105:577-581. |
| APA | Chen, Li.,Hu, Rui.,Xu, Jian.,Wang, Shuangqing.,Li, Xiyou.,...&Yang, Guoqiang.(2013).Third-order nonlinear optical properties of a series of porphyrin-appended europium(III) bis(phthalocyaninato) complexes.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,105,577-581. |
| MLA | Chen, Li,et al."Third-order nonlinear optical properties of a series of porphyrin-appended europium(III) bis(phthalocyaninato) complexes".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 105(2013):577-581. |
入库方式： OAI收割
来源：化学研究所
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