Gas-phase reactivity of aluminum cluster anions with ethanethiol: Carbon-sulfur bond activation
文献类型：期刊论文
| 作者 | Luo, Zhixun1,3; Smith, Jordan C.1; Berkdemir, Cueneyt1; Castleman, A. W., Jr.1,2 |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2013-12-18 |
| 卷号 | 590页码:63-68 |
| ISSN号 | 0009-2614 |
| DOI | 10.1016/j.cplett.2013.10.074 |
| 英文摘要 | We report a joint experimental and theoretical study of the gas-phase reactivity of Al cluster anions with ethanethiol (EtSH) in a fast-flow tube reactor. Nearly all Al-n(-) clusters observed are reactive at the presence of sufficient EtSH molecules with minor exceptions. Sulfide species AlnSm- dominate the observed reaction products, indicating C-S bond activation of EtSH. By using DFT calculations we provide an in-depth analysis on the interesting cluster reactivity of Al-n(-) with EtSH. It is demonstrated that the desulfurization leading to AlnSm- products is associated with the dehydrogen processes successively initiated by S-H bond cleavage and C-H bond cracking. (C) 2013 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000327721000010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46375]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Castleman, A. W., Jr. |
| 作者单位 | 1.Penn State Univ, Dept Chem, University Pk, PA 16802 USA 2.Penn State Univ, Dept Phys, University Pk, PA 16802 USA 3.Chinese Acad Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Zhixun,Smith, Jordan C.,Berkdemir, Cueneyt,et al. Gas-phase reactivity of aluminum cluster anions with ethanethiol: Carbon-sulfur bond activation[J]. CHEMICAL PHYSICS LETTERS,2013,590:63-68. |
| APA | Luo, Zhixun,Smith, Jordan C.,Berkdemir, Cueneyt,&Castleman, A. W., Jr..(2013).Gas-phase reactivity of aluminum cluster anions with ethanethiol: Carbon-sulfur bond activation.CHEMICAL PHYSICS LETTERS,590,63-68. |
| MLA | Luo, Zhixun,et al."Gas-phase reactivity of aluminum cluster anions with ethanethiol: Carbon-sulfur bond activation".CHEMICAL PHYSICS LETTERS 590(2013):63-68. |
入库方式： OAI收割
来源：化学研究所
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